Synthesis of fluorine-containing 1,3-dioxin-4-ones and their use for the synthesis of fluorinated compounds 含フッ素1,3-ジオキシン-4-オン類の合成とその含フッ素有機化合物への変換

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著者

    • 岩岡, 友保 イワオカ, トモヤス

書誌事項

タイトル

Synthesis of fluorine-containing 1,3-dioxin-4-ones and their use for the synthesis of fluorinated compounds

タイトル別名

含フッ素1,3-ジオキシン-4-オン類の合成とその含フッ素有機化合物への変換

著者名

岩岡, 友保

著者別名

イワオカ, トモヤス

学位授与大学

東北大学

取得学位

博士 (薬学)

学位授与番号

乙第6035号

学位授与年月日

1993-03-09

注記・抄録

博士論文

目次

  1. Contents / p1 (0003.jp2)
  2. Introduction / p1 (0004.jp2)
  3. I Synthesis of Fluorine-Containing Dioxinones / p7 (0007.jp2)
  4. I-1 Synthesis of 5-Fluoro-1,3-dioxin-4-ones / p7 (0007.jp2)
  5. I-2 Synthesis of 5-and 6-Trifluoromethyl-1,3-dioxin-4-ones / p12 (0010.jp2)
  6. II Synthesis of Fluorine-Containing Heterocycles / p15 (0011.jp2)
  7. II-1 By the [4+2]Cycloaddition of Acylketenes / p15 (0011.jp2)
  8. II-2 By the Acylacetylation of Nucleophiles / p20 (0014.jp2)
  9. III Synthesis of Fluorine-Containing β-Keto Esters / p23 (0015.jp2)
  10. IV Use of Fluorine-Containing 1,3-Dioxin-4-ones as the[数式]Components in Pericyclic Reactions / p27 (0017.jp2)
  11. IV-1 Diels-Alder Reaction by Use of the Dioxinones as Dienophiles / p27 (0017.jp2)
  12. IV-2 Photo[2+2]cycloaddition by Use of the Dioxinones as the Enone Components / p35 (0021.jp2)
  13. V Synthesis of Chiral α-Fluoro-β-keto Esters by the Diastereoselective Fluorination of Chiral Dioxinones / p37 (0022.jp2)
  14. VI Mechanism of cis Addition of Molecular Fluorine to Ethylenes / p44 (0026.jp2)
  15. VI-1 Qualitative Consideration for the Mechanism Based on HOMO-LUMO Theory and Principle of Maximum Overlapping / p45 (0026.jp2)
  16. VI-2 Quantitative Consideration for the Mechanism by Means of ab initio Calculation / p48 (0028.jp2)
  17. Conclusion / p53 (0030.jp2)
  18. Acknowledgements / p55 (0031.jp2)
  19. Experimental Section / p56 (0032.jp2)
  20. Experiments Related to Chapter I / p57 (0032.jp2)
  21. Experiments Related to Chapter II / p65 (0036.jp2)
  22. Experiments Related to Chapter III / p70 (0039.jp2)
  23. Experiments Related to Chapter IV / p72 (0040.jp2)
  24. Experiments Related to Chapter V / p80 (0044.jp2)
  25. References and Notes / p87 (0047.jp2)
  26. List of Papers / p94 (0051.jp2)
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各種コード

  • NII論文ID(NAID)
    500000095567
  • NII著者ID(NRID)
    • 8000000095793
  • DOI(NDL)
  • NDL書誌ID
    • 000000259881
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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