Stereoselective reactions of organocopper and organozinc reagents 有機銅試薬及び有機亜鉛試薬を用いた立体選択的反応

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著者

    • 荒井, 雅之 アライ, マサユキ

書誌事項

タイトル

Stereoselective reactions of organocopper and organozinc reagents

タイトル別名

有機銅試薬及び有機亜鉛試薬を用いた立体選択的反応

著者名

荒井, 雅之

著者別名

アライ, マサユキ

学位授与大学

東京工業大学

取得学位

博士 (理学)

学位授与番号

甲第2540号

学位授与年月日

1993-03-26

注記・抄録

博士論文

目次

  1. 論文目録 / (0002.jp2)
  2. Table of Contents / (0007.jp2)
  3. Chapter1 General Introduction.Development of Carbon-Carbon Bond Formation Reactions and Asymmetric lnduction / p1 (0011.jp2)
  4. 1.1 Nucleophilic Addition to α-Chiral Carbonyl Compound / p2 (0012.jp2)
  5. 1.2 Asymmetric Induction in the Nucleophilic Addition to Chiral Olefins / p5 (0015.jp2)
  6. Chapter2 High Diastereoselectivity in[化学式]-Allylation of Copper-Zinc Reagents / p14 (0024.jp2)
  7. 2.1 [化学式]Allylation with δ-Substituted Allylic Chlorides / p14 (0024.jp2)
  8. 2.2 δ-Substituted Allylic Chloride. Choice of the Substrate / p19 (0029.jp2)
  9. 2.3 [化学式] Allylation of δ-Alkoxyallylic Chlorides / p24 (0034.jp2)
  10. 2.4 [化学式] Allylation of δ-Substituted Allylic Chlorides.Steric Effect at Chiral Center / p33 (0043.jp2)
  11. 2.5 [化学式] Allylation of Silylcopper Reagent / p40 (0050.jp2)
  12. 2.6 Structure Determination / p41 (0051.jp2)
  13. 2.7 Conclusion / p47 (0057.jp2)
  14. 2.8 Experimental Section / p49 (0059.jp2)
  15. References / p76 (0086.jp2)
  16. Chapter3 0n the Nature of the Copper-Based[化学式]-Selective Reagents / p79 (0089.jp2)
  17. 3.1 lntroduction / p79 (0089.jp2)
  18. 3.2 Experimental Method / p83 (0093.jp2)
  19. 3.3 NMR Analysis of Copper-Zinc and Copper-Titanium Reagents / p85 (0095.jp2)
  20. 3.4 Reactivity Analysis of the Copper-Zinc and the Copper-Titanium Reagents / p94 (0104.jp2)
  21. 3.5 Conclusion / p98 (0108.jp2)
  22. References / p100 (0110.jp2)
  23. Chapter4 Copper-Catalyzed Reactions of Organotitanium Reagents.Highly Selective[化学式]-Allylation and Conjugate Addition / p102 (0112.jp2)
  24. 4.1 Introduction / p102 (0112.jp2)
  25. 4.2 [化学式]-Allylation Reaction of Organozinc-Based Catalytic Organocopper Reagents / p103 (0113.jp2)
  26. 4.3 [化学式]-Allylation of Organotitanium-Based Catalytic Organocopper Reagents / p106 (0116.jp2)
  27. 4.4 Conjugate Addition of Organotitanium-Based Catalytic Organocopper Reagents in the Presence of Me₃SiCl / p112 (0122.jp2)
  28. 4.5 Conclusion / p115 (0125.jp2)
  29. 4.6 Experimental Section / p116 (0126.jp2)
  30. References / p129 (0139.jp2)
  31. Chapter5 [化学式]-Allylation Reaction of Organozinc Reagents.Highly Regio-and Diastereoselective Reaction / p133 (0143.jp2)
  32. 5.1 lntroduction / p133 (0143.jp2)
  33. 5.2 [化学式]-Allylation Reaction of Organozinc Reagents / p135 (0145.jp2)
  34. 5.3 Asymmetric Induction in the[化学式]-Allylation of Dialkylzinc Reagents / p138 (0148.jp2)
  35. 5.4 [化学式]-Allylation of δ-Alkoxy Substituted Allylic Chlorides / p144 (0154.jp2)
  36. 5.5 Conclusion / p146 (0156.jp2)
  37. 5.6 Experimental Section / p147 (0157.jp2)
  38. References / p159 (0169.jp2)
  39. Chapter6 Stereochemistry of the[化学式]-Allylation Reaction / p161 (0171.jp2)
  40. 6.1 Observed Stereoselectivity in the Present[化学式]-Allylation Reactions / p161 (0171.jp2)
  41. 6.2 Distinctive Stereochemical Properties of the[化学式]-Allylation Reaction / p164 (0174.jp2)
  42. 6.3 Mechanism of the Present[化学式]-Allylation / p168 (0178.jp2)
  43. 6.4 Nucleophilic Carbon Mechanism.Explanation of Stereochemical Behavior / p171 (0181.jp2)
  44. 6.5 Conclusion / p178 (0188.jp2)
  45. References / p179 (0189.jp2)
  46. Chapter7 1,4-Asymmetric Induction in the 1,2-Addition to α,β-Unsaturated Aldehydes in the Presence of Chlorosilane.Vinylogous Cram's Rule / p181 (0191.jp2)
  47. 7.1 lntroduction / p181 (0191.jp2)
  48. 7.2 Vinylogous Cram's Rule / p182 (0192.jp2)
  49. 7.3 Conclusion / p188 (0198.jp2)
  50. 7.4 Experimental Section / p189 (0199.jp2)
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各種コード

  • NII論文ID(NAID)
    500000096881
  • NII著者ID(NRID)
    • 8000000097109
  • DOI(NDL)
  • NDL書誌ID
    • 000000261195
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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