Syntheses and reactions of functionalized α,α-difluorinated aldehyde equivalents 官能基を含むα,α-ジフルオロアルデヒド等価体の合成とその反応

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著者

    • 塚本, 尚 ツカモト, タカシ

書誌事項

タイトル

Syntheses and reactions of functionalized α,α-difluorinated aldehyde equivalents

タイトル別名

官能基を含むα,α-ジフルオロアルデヒド等価体の合成とその反応

著者名

塚本, 尚

著者別名

ツカモト, タカシ

学位授与大学

東京工業大学

取得学位

博士 (工学)

学位授与番号

甲第2570号

学位授与年月日

1993-03-26

注記・抄録

博士論文

目次

  1. 論文目録 / (0002.jp2)
  2. Contents / p2 (0004.jp2)
  3. Chapter1 Introduction / p1 (0007.jp2)
  4. References and Notes / p17 (0023.jp2)
  5. Chapter2 Formylation Reaction of α,α-Difluorinated Reformatsky Reagents / p20 (0026.jp2)
  6. Introduction / p20 (0026.jp2)
  7. Reaction Mechanism and Optimization of the Conditions / p22 (0028.jp2)
  8. CF₂-Containing Hemiacetals and Malonates / p25 (0031.jp2)
  9. Formylation Reaction of Difluoromethylphosphonate / p28 (0034.jp2)
  10. Experimental / p32 (0038.jp2)
  11. References and Notes / p38 (0044.jp2)
  12. Chapter3 Reaction of α,α-Difluorinated Hemiacetals as Aldehdye Equivalents / p41 (0047.jp2)
  13. Introduction / p41 (0047.jp2)
  14. Lewis Acid-promoted Reactions with Nucleophiles / p44 (0050.jp2)
  15. Horner-Wadsworth-Emmons Reaction / p47 (0053.jp2)
  16. Nitroaldol Reaction / p48 (0054.jp2)
  17. Reaction of α,α-Difluoro-a-phosphonoacetaldehdye Ethyl Hemiacetal / p56 (0062.jp2)
  18. Experimental / p60 (0066.jp2)
  19. References and Notes / p73 (0079.jp2)
  20. Chapter4 Synthesis of β,β-Difluorinated Amines from CF₂-Containing N,0-Acetal or Imine / p76 (0082.jp2)
  21. Introduction / p76 (0082.jp2)
  22. Difluorinated N,O-Acetal / p83 (0089.jp2)
  23. Difluorinated N-Benzylamine / p88 (0094.jp2)
  24. Experimental / p94 (0100.jp2)
  25. References and Notes / p104 (0110.jp2)
  26. Chapter5 Synthesis of α,α,α',α'-Tetrafluoroketone A Novel Transition-State Analogue for Carbonate Hydrolysis / p106 (0112.jp2)
  27. Introduction / p106 (0112.jp2)
  28. Reformatsky Reaction of Ethyl 4-Chloro-4,4-difluorocrotonate / p111 (0117.jp2)
  29. Horner-Wadsworth-Emmons Reactions of α,α-Difluoro-b-hydroxyaldehdye Equivalent / p117 (0123.jp2)
  30. Synthesis of α,α,α',α'-Tetrafluoroketone / p121 (0127.jp2)
  31. Experimental / p126 (0132.jp2)
  32. References and Notes / p139 (0145.jp2)
  33. Chapter6 Conclusion / p141 (0147.jp2)
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各種コード

  • NII論文ID(NAID)
    500000096911
  • NII著者ID(NRID)
    • 8000000097139
  • DOI(NDL)
  • NDL書誌ID
    • 000000261225
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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