Intercalation chemistry of transition metal complex anions in Mg-Al layered double hydroxides and their properties 合成ハイドロタルサイト層間への遷移金属錯体陰イオンのインターカレーションとキャラクタリゼーション
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Bibliographic Information
- Title
-
Intercalation chemistry of transition metal complex anions in Mg-Al layered double hydroxides and their properties
- Other Title
-
合成ハイドロタルサイト層間への遷移金属錯体陰イオンのインターカレーションとキャラクタリゼーション
- Author
-
Lopez-Salinas, Esteban
- Author(Another name)
-
ロペス サリナス, エステバン
- University
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東京工業大学
- Types of degree
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博士 (工学)
- Grant ID
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甲第2576号
- Degree year
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1993-03-26
Note and Description
博士論文
Table of Contents
- 論文目録 / (0002.jp2)
- LIST OF CONTENTS / p3 (0005.jp2)
- CHAPTER1 Introduction / p1 (0012.jp2)
- 1.1 Anionic clays. / p1 (0012.jp2)
- 1.2 Nomenclature. / p2 (0013.jp2)
- 1.3 The Structure of hydrotalcite. / p2 (0013.jp2)
- 1.4 Minerals of the pyroaurite and sjogrenite groups. / p5 (0016.jp2)
- 1.5 Layered double hydroxides with a formula:[化学式]･mH₂O / p5 (0016.jp2)
- 1.6 Layered double hydroxides with formul[化学式]･mH₂O / p13 (0024.jp2)
- 1.7 Physicochemical characterization. / p14 (0025.jp2)
- 1.8 Preparative methods. / p19 (0030.jp2)
- 1.9 Applications of layered double hydroxides. / p23 (0034.jp2)
- 1.10 Scope of this Study. / p27 (0038.jp2)
- 1.11 References. / p34 (0045.jp2)
- CHAPTER2 Intercalation Chemistry of a Mg-Al Layered Double Hydroxide Ion-exchanged with Complex MCl₄²¯(M=Ni,Co)Ions from Organic Media / p42 (0053.jp2)
- 2.1 Introduction. / p42 (0053.jp2)
- 2.2 Experimental. / p44 (0055.jp2)
- 2.3 Characterization. / p47 (0058.jp2)
- 2.4 Results and discussion. / p49 (0060.jp2)
- 2.5 Conclusions. / p69 (0080.jp2)
- 2.6 References. / p70 (0081.jp2)
- CHAPTER3 Reactivity of interstitial Cl¯ anions in Mg₆Al₂(OH)₁₆Cl₂･4H₂O in the halide exchange reaction with alkyl halides. / p73 (0084.jp2)
- 3.1 Introduction. / p73 (0084.jp2)
- 3.2 Experimental. / p74 (0085.jp2)
- 3.3 Results and discussion. / p75 (0086.jp2)
- 3.4 Conclusions. / p86 (0097.jp2)
- 3.5 References. / p86 (0097.jp2)
- CHAPTER4 Reactivity of Interstitial[NiCl₄]²¯ Anions in a Mg-Al Hydrotalcite-like Clay towards Alkyl Bromides in the Liquid-phase. / p88 (0099.jp2)
- 4.1 Introduction. / p88 (0099.jp2)
- 4.2 Experimental. / p89 (0100.jp2)
- 4.3 Reactivity of Cl¯ ligands in NiCl-HT towards alkyl bromides. / p90 (0101.jp2)
- 4.4 Conclusions. / p101 (0112.jp2)
- 4.5 References. / p102 (0113.jp2)
- CHAPTER5 Thermal Transformation of a Mg-Al Layered Double Hydroxide Pillared with Decavanadate Isopolyanions. / (0115.jp2)
- 5.1 Introduction. / p104 (0115.jp2)
- 5.2 Experimental. / p105 (0116.jp2)
- 5.3 Results and discussion. / p108 (0119.jp2)
- 5.4 General discussion. / p121 (0132.jp2)
- 5.5 References. / p122 (0133.jp2)
- CHAPTER6 Interaction of Polar Substrates with Transition Metal Substituted Keggin-type Heteropolyanions[XSiW₁₁O₃₉]⁶⁻(X=Co²⁺,Mn²⁺)Pillared in a Mg-Al Layered Double Hydroxide. / p124 (0135.jp2)
- 6.1 Introduction. / p124 (0135.jp2)
- 6.2 Experimental. / p125 (0136.jp2)
- 6.3 Composition of the pillared LDHs. / p131 (0142.jp2)
- 6.4 Pillaring of[Co(H₂O)SiW₁₁O₃₉]⁶⁻ anions into a Zn₂Al-LDH. / p133 (0144.jp2)
- 6.5 Pillaring of[Co(H₂0)SiW₁₁O₃₉]⁶⁻ anions into a Mg₂Al LDH. / p136 (0147.jp2)
- 6.6 Pillaring of[Mn(H₂O)SiW₁₁O₃₉]⁶⁻ anions into a Mg₂Al-LDH. / p138 (0149.jp2)
- 6.7 Thermal stability of the pillared heteropolyanions as examined by IR spectroscopy. / p140 (0151.jp2)
- 6.8 Coordination environment of Co(II)in the pillared[Co(H₂0)SiW₁₁O₃₉]. / p143 (0154.jp2)
- 6.9 Mn(II)in MnHPA-Mg₂Al as analyzed by ESR spectroscopy. / p156 (0167.jp2)
- 6.10 Conclusions. / p159 (0170.jp2)
- 6.11 References. / p160 (0171.jp2)
- CHAPTER7 General conclusions and future possibilities. / p162 (0173.jp2)
- Acknowledgments / p167 (0178.jp2)