Complexation and structure of lanthanoid(Ⅲ) ions in nonaqueous solution 非水溶液中におけるランタノイド(Ⅲ)イオンの錯形成及び構造

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Author

    • 高橋, 陵太 タカハシ, リョウタ

Bibliographic Information

Title

Complexation and structure of lanthanoid(Ⅲ) ions in nonaqueous solution

Other Title

非水溶液中におけるランタノイド(Ⅲ)イオンの錯形成及び構造

Author

高橋, 陵太

Author(Another name)

タカハシ, リョウタ

University

東京工業大学

Types of degree

博士 (理学)

Grant ID

甲第2633号

Degree year

1993-03-26

Note and Description

博士論文

Table of Contents

  1. Contents / (0004.jp2)
  2. 1 Introduction / p1 (0007.jp2)
  3. 1.1 Discovery of rare earth elements / p1 (0007.jp2)
  4. 1.2 Quest for separation reveals chemistry of rare earths / p5 (0011.jp2)
  5. 1.3 Complex formation of lanthanoid(III) ions with chelating agents in aqueous solution / p6 (0012.jp2)
  6. 1.4 Coordination geometries of hydrated lanthanoid(III) ions / p8 (0014.jp2)
  7. 1.5 Lanthanoid(III) ions in nonaqueous solution / p13 (0019.jp2)
  8. 1.6 Formation of outer or inner-sphere complex in solution / p18 (0025.jp2)
  9. 1.7 Scandium(III), aluminium(III), gallium(III) and indium(III) ions in water or nonaqueous solution / p20 (0027.jp2)
  10. 1.8 Experimental aspects / p22 (0029.jp2)
  11. 1.9 The purpose of this study / p25 (0032.jp2)
  12. References / p29 (0036.jp2)
  13. 2 Experimental / p35 (0042.jp2)
  14. 2.1 Calorimetric measurement / p35 (0042.jp2)
  15. 2.2 EXAFS measurements / p40 (0047.jp2)
  16. References / p44 (0051.jp2)
  17. 3 Thermodynamics of Chloro Complex Formation of Lanthanoid(III) ions in N, N-Dimethylformamide / p45 (0052.jp2)
  18. 3.1 Introduction / p45 (0052.jp2)
  19. 3.2 Experimental / p45 (0052.jp2)
  20. 3.3 Results / p48 (0055.jp2)
  21. 3.4 Discussion / p58 (0065.jp2)
  22. References / p61 (0068.jp2)
  23. 4 Inner-sphere and Outer-sphere Complex Formation of Yttrium(III) and Lanthanoid(III) in N, N-Dimethylformamide / p62 (0069.jp2)
  24. 4.1 Introduction / p62 (0069.jp2)
  25. 4.2 Experimental / p63 (0070.jp2)
  26. 4.3 Results / p66 (0073.jp2)
  27. 4.4 Discussion / p75 (0082.jp2)
  28. References / p79 (0086.jp2)
  29. 5 The Structure of Solvated Lanthanoid(III) Ions in N, N-Dimethylformamide and N, N-Dimethylacetamide, and Complex Formation of Halogeno Lanthanoid(III) in N, N-Dimethylacetamide / p81 (0088.jp2)
  30. 5.1 Introduction / p81 (0088.jp2)
  31. 5.2 Experimental / p82 (0089.jp2)
  32. 5.3 Results / p89 (0096.jp2)
  33. 5.4 Discussion / p109 (0116.jp2)
  34. References / p116 (0119.jp2)
  35. 6 Thiocyanato Complex Formation of Yttrium(III) and Lanthanoid(III) Ions in N, N-Dimethylformamide / p117 (0120.jp2)
  36. 6.1 Introduction / p117 (0120.jp2)
  37. 6.2 Experimental / p118 (0121.jp2)
  38. 6.3 Results / p121 (0124.jp2)
  39. 6.4 Discussion / p135 (0138.jp2)
  40. References / p139 (0142.jp2)
  41. 7 Halogeno and Thiocyanato Complex Formation of Aluminium,Gallium(III) and Indium(III) Ions in N,N-Dimethylformamide / p140 (0143.jp2)
  42. 7.1 Introduction / p140 (0143.jp2)
  43. 7.2 Experimental / p141 (0144.jp2)
  44. 7.3 Results / p144 (0147.jp2)
  45. 7.4 Discussion / p156 (0159.jp2)
  46. References / p160 (0163.jp2)
  47. 8 Conclusion / p161 (0164.jp2)
  48. Appendix / p167 (0170.jp2)
  49. List of Publications / (0188.jp2)
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Codes

  • NII Article ID (NAID)
    500000096974
  • NII Author ID (NRID)
    • 8000000097202
  • DOI(NDL)
  • NDLBibID
    • 000000261288
  • Source
    • NDL ONLINE
    • NDL Digital Collections

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