Crystalline-state photoisomerization of cobaloxime complexes コバロキシム錯体の結晶相光異性反応
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Bibliographic Information
- Title
-
Crystalline-state photoisomerization of cobaloxime complexes
- Other Title
-
コバロキシム錯体の結晶相光異性反応
- Author
-
関根, あき子
- Author(Another name)
-
セキネ, アキコ
- University
-
東京工業大学
- Types of degree
-
博士 (理学)
- Grant ID
-
乙第2433号
- Degree year
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1993-02-28
Note and Description
博士論文
identifier:oai:t2r2.star.titech.ac.jp:99000861
Table of Contents
- 論文目録 / (0002.jp2)
- Contents / p2 (0006.jp2)
- Acknowledgements / p1 (0005.jp2)
- Contents / p2 (0006.jp2)
- Chapter1 Introduction / (0009.jp2)
- 1-1 Solid state reaction / p2 (0010.jp2)
- 1-2 Examples of solid-state reactions / p5 (0013.jp2)
- 1-3 Merits of solid-state reaction / p17 (0025.jp2)
- 1-4 Cavity and reaction cavity / p18 (0026.jp2)
- 1-5 Crystalline-state racemization / p22 (0030.jp2)
- 1-6 Photoisomerization of cobaloxime complexes / p29 (0037.jp2)
- References / p33 (0041.jp2)
- Chapter2 Solid State β-α Photoisomerization of β-Cyanoethyl Cobaloxime Complexes / (0044.jp2)
- 2-1 Structures of (β-Cyanoethyl)(3-ethylpyridine)bis(dimethyl glyoximato)cobalt(III) and (β-Cyanoethyl)(4-ethylpyridine)bis (dimethylglyoximato)cobalt(III) / p37 (0045.jp2)
- 2-2 Structures of (β-Cyanoethyl)(3-cyanopyridine)bis(dimethylgly-oximato)cobalt(III) monohydrate (3cp) and (β-Cyanoethyl)(4-aminopyridine)bis(dimethylglyoximato)cobalt(III)(4ap) / p48 (0056.jp2)
- 2-3 Structures of (β-Cyanoethyl)(piperidine)bis(dimethylgly-oximato)cobalt(III) / p59 (0067.jp2)
- 2-4 Structures of (β-Cyanoethyl)(3-aminopyridine)bis(dimethylgly-oximato)cobalt(III)(3ap) and (β-Cyanoethyl)aniline)bis dimethylglyoximato)cobalt(III)(1ab) / p69 (0077.jp2)
- 2-5 Accelerated Reaction Rate by Hydrogen Bond / p82 (0090.jp2)
- References / p87 (0095.jp2)
- Chapter3 Crystalline State β-α Photoisomerization and Generation of Asymmetry in a Chiral Crystal Environment / (0097.jp2)
- 3-1 Introduction / p90 (0098.jp2)
- 3-2 Experimental / p92 (0100.jp2)
- 3-3 Results / p96 (0104.jp2)
- 3-4 Discussion / p109 (0117.jp2)
- References / p116 (0124.jp2)
- Chapter4 β-α Photoisomerization of the mixed crystal composed of β- and α-cyanoethyl complexes in the solid state and crystalline state / (0126.jp2)
- 4-1 Introduction / p119 (0127.jp2)
- 4-2 Experimental / p120 (0128.jp2)
- 4-3 Results / p124 (0132.jp2)
- 4-4 Discussion / p133 (0141.jp2)
- References / p139 (0147.jp2)
- Chapter5 Comparison of Solid-State and Crystalline-State Isomerizations in Three Kinds of Cobaloxime Complex Crystals / p140 (0148.jp2)
- 5-1 Introduction / p141 (0149.jp2)
- 5-2 Experimental / p142 (0150.jp2)
- 5-3 Results / p151 (0159.jp2)
- 5-4 Discussion / p188 (0196.jp2)
- References / p193 (0201.jp2)
- Chapter6 Conclusion / (0202.jp2)