Thermoreversible gelation and electrical properties of polydiacetylene/solvent systems ポリジアセチレン/溶媒系の熱可逆ゾル-ゲル転移と電気伝導性
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著者
書誌事項
- タイトル
-
Thermoreversible gelation and electrical properties of polydiacetylene/solvent systems
- タイトル別名
-
ポリジアセチレン/溶媒系の熱可逆ゾル-ゲル転移と電気伝導性
- 著者名
-
陳, 平凡
- 著者別名
-
チェン, ピンファン
- 学位授与大学
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大阪大学
- 取得学位
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博士 (理学)
- 学位授与番号
-
甲第4864号
- 学位授与年月日
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1993-09-27
注記・抄録
博士論文
目次
- CONTENTS / p5 (0004.jp2)
- Chapter1.GENERAL INTRODUCTION / p1 (0006.jp2)
- 1-1.Gelation / p1 (0006.jp2)
- 1-2.Electronically Conductive Polymers / p2 (0007.jp2)
- 1-3.Properties of Urethane-Substituted Polydiacetylenes / p4 (0008.jp2)
- 1-4.Scope and Outline of This Thesis / p5 (0008.jp2)
- References / p8 (0010.jp2)
- Chapter2.MATERIALS AND METHODS / p11 (0011.jp2)
- 2-1.Polydiacetylene Samples and Other Chemicals / p11 (0011.jp2)
- 2-2.Methods of Physical Property Measurements / p14 (0013.jp2)
- References / p21 (0016.jp2)
- Chapter3.PHYSICAL PROPERTIES AND SOL-GEL TRANSITION OF P(4BCMU)AND P(3BCMU)GELS / p22 (0017.jp2)
- 3-1.Introduction / p22 (0017.jp2)
- 3-2.Mechanical Properties and Sol-Gel Transition / p24 (0018.jp2)
- 3-3.Characteristic Temperatures Associated with Sol-Gel Transition / p33 (0022.jp2)
- 3-4.Optical Properties and Color Change / p40 (0026.jp2)
- 3-5.Molecular Weight and Concentration Dependences of Transition Temperatures / p46 (0029.jp2)
- 3-6.Summary and Conclusion / p52 (0032.jp2)
- References / p54 (0033.jp2)
- Chapter4.ELECTRIC CONDUCTION IN GELS / p55 (0033.jp2)
- 4-1.Introduction / p55 (0033.jp2)
- 4-2.Electronic and Ionic Conductivities / p57 (0034.jp2)
- 4-3.Temperature Dependence of Electronic Conductivity / p68 (0040.jp2)
- 4-4.Analyses of Moduli and Conductivity by Percolation Model / p75 (0043.jp2)
- 4-5.Molecular Aspects of Electronic Conduction in the Gel / p83 (0047.jp2)
- 4-6.Conclusion / p95 (0053.jp2)
- References / p97 (0054.jp2)
- Chapter5.SOL-GEL TRANSITION AND MECHANISM OF GELATION / p100 (0056.jp2)
- 5-1.Introduction / p100 (0056.jp2)
- 5-2.Concentration Dependence of Transition Temperatures / p102 (0057.jp2)
- 5-3.Conformation of P(4BCMU)and P(3BCMU)Chains / p103 (0057.jp2)
- 5-4.Effect of Solvent Quality on Transition Temperature / p104 (0058.jp2)
- 5-5.Hydrogen Bonding / p106 (0059.jp2)
- 5-6.Crystallinity of P(3BCMU)gel / p122 (0067.jp2)
- 5-7.Conclusion / p126 (0069.jp2)
- References / p131 (0071.jp2)
- Chapter6.BLEND GEL OF P(3BCMU)AND P(4BCMU) / p133 (0072.jp2)
- 6-1.Introduction / p133 (0072.jp2)
- 6-2.Gel-to-Sol Transition Temperature and Shear Moduli / p134 (0073.jp2)
- 6-3.Conductivity in Blend Gels / p138 (0075.jp2)
- 6-4.UV Spectra and Color Change / p141 (0076.jp2)
- 6-5.Conclusions / p147 (0079.jp2)
- References / p148 (0080.jp2)
- Chapter7.CONCLUSIONS / p149 (0080.jp2)
- List of Abbreviations and symbols / p154 (0083.jp2)
- List of Publications / p156 (0084.jp2)
