Studies on the structure and reactions of strained cage hydrocarbons and related carbocations 歪かご形炭化水素ならびに関連カルボカチオンの構造と反応に関する研究

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著者

    • 岡崎, 隆男 オカザキ, タカオ

書誌事項

タイトル

Studies on the structure and reactions of strained cage hydrocarbons and related carbocations

タイトル別名

歪かご形炭化水素ならびに関連カルボカチオンの構造と反応に関する研究

著者名

岡崎, 隆男

著者別名

オカザキ, タカオ

学位授与大学

京都大学

取得学位

博士 (工学)

学位授与番号

甲第6423号

学位授与年月日

1996-03-23

注記・抄録

博士論文

目次

  1. 論文目録 / (0001.jp2)
  2. Contents / p3 (0005.jp2)
  3. Preface / p5 (0006.jp2)
  4. Acknowledgments / p22 (0015.jp2)
  5. List of Publications / p23 (0015.jp2)
  6. Part1.Structure and Reactions of 4-Homoadamantyl and Related Carbocations / p1 (0016.jp2)
  7. Chapter1.Solvolysis of〔3-¹³C〕-4-Homoadamantyl p-Toluenesulfonate.Limited Degeneracy of 4-Homoadamantyl Cation via Multiple Wagner-Meerwein Rearrangement and Vicinal Hydride Shifts under Solvolytic Conditions / p3 (0017.jp2)
  8. Chapter2.Solvolysis of 3-Substituted 4-Homoadamantyl Methanesulfonates.Can β-Substituent Effect Distinguish between Classical and Nonclassical Ion Intermediates? / p30 (0031.jp2)
  9. Chapter3.Solvolysis of〔3-¹³C〕-3,4-Dimethyl-4-homoadamantyl p-Nitrobenzoate.Comparison of the Wagner-Meerwein Rearrangement Barriers of the Secondary and Tertiary 4-Homoadamantyl Cations / p53 (0042.jp2)
  10. Chapter4.Acid-isomerization of 3,4-Dimethyl-4-homoadamantyl Cation to 3-Ethyl-5-methyl-1-adamantyl Cation.A Novel Method for Construction of an Adamantyl Framework Having Two Alkyl Groups on the Bridgehead Positions / p127 (0079.jp2)
  11. Chapter5.Solvolyses of 4-Methylene-2ax-and-2eq-Adamantyl p-Toluenesulfonates:Intermediacy of Classical Carbocation in the Axial and π-Bridged Carbocation in the Equatorial p-Toluenesulfonate Solvolyses / p138 (0085.jp2)
  12. Part2.Generation and Reactions of Novel 2-Substituted Adamantenes / p157 (0094.jp2)
  13. Chapter6.Generation and Reactivity of 2-Aryladamantenes.Polarization of the Twisted Double Bond / p159 (0095.jp2)
  14. Chapter7.Steric Effects of Alkyl Group on the Reactivity of 2-Alkyladamantenes / p190 (0111.jp2)
  15. Chapter8.Generation and Reactivity of 2-(l-Adamantyl)adamantene.Reversion to 3-(1-Adamantyl)-4-protoadamantylidene / p207 (0119.jp2)
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各種コード

  • NII論文ID(NAID)
    500000131147
  • NII著者ID(NRID)
    • 8000000965839
  • DOI(NDL)
  • NDL書誌ID
    • 000000295461
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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