Synthetic studies of stereoregular polysaccharides : influence of substituent group on ring-opening polymerization 立体規則性多糖の合成研究 : 開環重合における置換基の影響

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著者

    • 上高原, 浩 カミタカハラ, ヒロシ

書誌事項

タイトル

Synthetic studies of stereoregular polysaccharides : influence of substituent group on ring-opening polymerization

タイトル別名

立体規則性多糖の合成研究 : 開環重合における置換基の影響

著者名

上高原, 浩

著者別名

カミタカハラ, ヒロシ

学位授与大学

京都大学

取得学位

博士 (農学)

学位授与番号

甲第6478号

学位授与年月日

1996-03-23

注記・抄録

博士論文

目次

  1. 論文目録 / (0001.jp2)
  2. CONTENTS / p1 (0004.jp2)
  3. INTRODUCTION / p1 (0008.jp2)
  4. CHAPTER1 Selection and synthesis of 1,4-anhydro-α-D-glucopyranose derivatives:starting materials for ring-opening polymerization / p5 (0010.jp2)
  5. Introduction / p5 (0010.jp2)
  6. 1.1 Synthesis of l,4-anhydro-2,3-di-O-benzyl-6-O-pivaloyl-α-D-glucopyranose(1) / p6 (0011.jp2)
  7. 1.2 Synthesis of l,4-anhydro-3,6-di-0-benzyl-2-0-pivaloyl-α-D-glucopyranose(2) / p8 (0012.jp2)
  8. 1.3 Synthesis of l,4-anhydro-3-0-benzyl-2,6-di-0-pivaloyl-α-D-glucopyranose(3) / p10 (0013.jp2)
  9. 1.4 Synthesis of l,4-anhydro-6-O-benzyl-2,3-di-O-pivaloyl-α-D-glucopyranose(4) / p11 (0013.jp2)
  10. 1.5 Summary / p11 (0013.jp2)
  11. CHAPTER2 Ring-opening polymerization of 1,4-anhydro-α-D-glucopyranose derivatives / p14 (0015.jp2)
  12. Introduction / p14 (0015.jp2)
  13. 2.1 Ring-opening polymerization of 1,4-anhydro-α-D-glucopyranose derivatives / p15 (0015.jp2)
  14. 2.2 Substituent effects on ring-opening polymerization of 1,4-anhydro-α-D-glucopyranose derivatives / p28 (0022.jp2)
  15. 2.3 Deprotection of substituted polymers / p33 (0024.jp2)
  16. 2.4 Summary / p36 (0026.jp2)
  17. CHAPTER3 Selection and synthesis of α-D-glucopyranose 1,2,4-orthopivalate derivatives:starting materials for ring-opening polymerization / p38 (0027.jp2)
  18. Introduction / p38 (0027.jp2)
  19. 3.1 Syntheses of 3,6-di-O-benzyl-α-D-glucopyranose 1,2,4-orthopivalate(5),3-0-benzyl-6-O-pivaloyl-α-D-glucopyranose 1,2,4-orthopivalate(6),6-O-benzyl-3-0-pivaloyl-α-D-glucopyranose 1,2,4-orthopivalate(7),and 3,6-di-O-pivaloyl-α-D-glucopyranose 1,2,4-orthopivalate(8) / p39 (0027.jp2)
  20. 3.2 ¹H-NMR Chemical shifts of α-D-glucopyranose 1,2,4-orthopivalate derivatives / p41 (0028.jp2)
  21. 3.3 Summary / p43 (0029.jp2)
  22. CHAPTER4 Ring-opening polymerization of α-D-glucopyranose 1,2,4-orthopivalate derivatives / p44 (0030.jp2)
  23. Introduction / p44 (0030.jp2)
  24. 4.1 Ring-opening polymerization of α-D-glucopyranose 1,2,4-orthopivalate derivative / p46 (0031.jp2)
  25. 4.2 Substituent effect on ring-opening polymerization of α-D-glucopyranose 1,2,4- orthopivalate derivatives / p56 (0036.jp2)
  26. 4.3 Conversion of the poly(5)s into cellulose(34)via cellulose triacetate(CTA)(33) / p64 (0040.jp2)
  27. 4.4 Summary / p69 (0042.jp2)
  28. CONCLUSIONS / p71 (0043.jp2)
  29. EXPERIMENTAL SECTION / p75 (0045.jp2)
  30. REFERENCES / p93 (0054.jp2)
  31. ACKNOWLEDGMENTS / p97 (0056.jp2)
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各種コード

  • NII論文ID(NAID)
    500000131202
  • NII著者ID(NRID)
    • 8000000965887
  • DOI(NDL)
  • NDL書誌ID
    • 000000295516
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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