Synthesis, structure, and dynamic behavior of polyoxovanadate V[4]O[12][4-] supported organorhodium(Ⅰ) and -iridium(Ⅰ) complexes
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著者
書誌事項
- タイトル
-
Synthesis, structure, and dynamic behavior of polyoxovanadate V[4]O[12][4-] supported organorhodium(Ⅰ) and -iridium(Ⅰ) complexes
- 著者名
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木田, 克彦
- 著者別名
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キダ, カツヒコ
- 学位授与大学
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関西学院大学
- 取得学位
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博士 (理学)
- 学位授与番号
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甲第86号
- 学位授与年月日
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1996-03-25
注記・抄録
博士論文
目次
- Table of Contents / p2 (0004.jp2)
- Chapter One:Introduction / p1 (0007.jp2)
- References and Notes / p8 (0014.jp2)
- Chapter Two:Metal Oxide Clusters as Building Blocks:Synthesis and Structure of 〔Rh(COD)V₄O₁₂〕³⁻ and 〔{Rh(COD)}₂V₄O₁₂〕²⁻ / p10 (0017.jp2)
- Introduction / p10 (0017.jp2)
- Experimental / p12 (0019.jp2)
- Results and Discussion / p16 (0023.jp2)
- References and Notes / p30 (0037.jp2)
- Chapter Three:Cyclooctadienerhodium(I) Fragments Pivot on Tetravanadate Surface:A ¹H, ¹³C, ¹⁷O, and ⁵¹V NMR Study of 〔Rh(COD)V₄O₁₂〕³⁻ and 〔{Rh(COD)}₂V₄O₁₂〕²⁻ / p31 (0039.jp2)
- Introduction / p31 (0039.jp2)
- Experimental / p32 (0040.jp2)
- Results / p37 (0045.jp2)
- Discussion / p53 (0061.jp2)
- References and Notes / p55 (0063.jp2)
- Chapter Four:Isomers Induced by Intramolecular Pivot Rearrangement:Synthesis, Solid State Structure, and Solution Dynamics of 〔{Rh(C₆H₁₀)}₂V₄O₁₂〕²⁻ and 〔{Rh(C₈H₁₄)}₂V₄O₁₂〕²⁻ / p56 (0065.jp2)
- Introduction / p56 (0065.jp2)
- Experimental / p58 (0067.jp2)
- Results / p65 (0074.jp2)
- Discussion / p92 (0101.jp2)
- References and Notes / p94 (0103.jp2)
- Chapter Five:Quantitative Dynamic Studies:Synthesis and Characterization of the Type [化学式]⁽⁴⁻ⁿ⁾⁻(n=1,2;M=Rh,Ir;LL=2 octene, COD, NBD, C₆H₁₀, C₈H₁₄) Anions / p95 (0105.jp2)
- Introduction / p95 (0105.jp2)
- Experimental / p96 (0106.jp2)
- Results and Discussion / p101 (0111.jp2)
- References and Notes / p121 (0131.jp2)
- Appendixes / p122 (0133.jp2)