Stereoselective synthesis of (E) -alkene dipeptide isosteres via organocopper mediated S[N]2'-reactions 有機銅試薬によるS[N]2'型置換反応を用いた (E) -アルケン・ジペプチド・イソスターの立体選択的な合成法に関する研究
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著者
書誌事項
- タイトル
-
Stereoselective synthesis of (E) -alkene dipeptide isosteres via organocopper mediated S[N]2'-reactions
- タイトル別名
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有機銅試薬によるS[N]2'型置換反応を用いた (E) -アルケン・ジペプチド・イソスターの立体選択的な合成法に関する研究
- 著者名
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巾下, 広
- 著者別名
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ハバシタ, ヒロム
- 学位授与大学
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京都大学
- 取得学位
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博士 (薬学)
- 学位授与番号
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乙第9620号
- 学位授与年月日
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1997-05-23
注記・抄録
博士論文
目次
- 論文目録 / (0001.jp2)
- Contents / (0006.jp2)
- Preface / p1 (0007.jp2)
- Chapter1 Stereoselective Synthesis of(E)-Alkene Dipeptide Isosteres via Organocyanocuprate-BF₃ Mediated [化学式]-Reaction and Determination of the Absolute Configuration of the Alkyl Group at the α-Position in the Acyclic α-Alkyl-(E)-β,γ-Enoates by Circular Dichroism / p9 (0011.jp2)
- Section1.Stereoselective Synthesis of (E)-Alkene Dipeptide Isosteres via Organocyanocuprate-BF₃ Mediated [化学式]-Reaction / p9 (0011.jp2)
- Section2.Determination of the Absolute Configuration of the Alkyl Group at the α-Position in the Acyclic α-Alkyl-(E)-β,γ-Enoates by Circular Dichroism / p49 (0031.jp2)
- Chapter2.Reaction of γ-Mesyloxy-α,β-Enoates Derived from Serine or Threonine with Organocopper Reagents / p59 (0036.jp2)
- Section1.Syn-[化学式] Pathway in the Reaction of Certain γ-Mesyloxy-α,β-Enoates with RCu(CN)MgX･BF₃ Reagents.Importance of MgX and Bulky R Group upon the Diastereoselectivity / p59 (0036.jp2)
- Section2.Synthesis of (E)-Alkene Dipeptide Isosteres Free from Reduction Products by the Use of Organozinc Reagents in the Presence of Copper- and Lithium Salts / p91 (0052.jp2)
- Part1.Higher Order Zinc Cuprates Involving Lithium Chloride:Synthesis of (E)-Alkene Dipeptide Isosteres Free from Reduction Products / p91 (0052.jp2)
- Part2.[化学式] Selective Alkylation of γ-Mesyloxy-α,β-Enoates with RZnX Reagents Generated from Grignard Reagents,Zinc Chloride,Lithium Chloride,and Cu(II)-Salts / p103 (0058.jp2)
- Chapter3 Conclusions / p109 (0061.jp2)
- Acknowledgments / p111 (0062.jp2)
- List of publications / p113 (0063.jp2)