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シアル酸の研究 : KDNグリコシル誘導体の合成とKDNグリカールの化学

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著者

    • 孫, 学龍 スン, シュェロン

書誌事項

タイトル

シアル酸の研究 : KDNグリコシル誘導体の合成とKDNグリカールの化学

著者名

孫, 学龍

著者別名

スン, シュェロン

学位授与大学

北里大学

取得学位

博士 (薬学)

学位授与番号

甲第270号

学位授与年月日

1997-03-21

注記・抄録

博士論文

目次

  1. CONTENTS / p1 (0004.jp2)
  2. GENERAL PART / p1 (0009.jp2)
  3. INTRODUCTION / p2 (0010.jp2)
  4. PartI Syntheses of KDN(3-deoxy-D-glycero-D-galacto-nonulosonic acid)glycosyl derivatives / p6 (0014.jp2)
  5. Chapter1 Preparation of KDN / p6 (0014.jp2)
  6. Chapter2 Syntheses of N-glycosides of KDN / p10 (0018.jp2)
  7. 2.1 Syntheses of N-glycosides of KDN / p10 (0018.jp2)
  8. 2.2 Photocycloaddition of N-glycoside of KDN with2,3-dimethyl-2-butene / p16 (0024.jp2)
  9. 2.3 Mechanism of the photocycloaddition of N-glycoside of KDN with 2,3-dimethyl-2-butene / p21 (0029.jp2)
  10. Chapter3 Syntheses of O-glycosides of KDN / p25 (0033.jp2)
  11. 3.1 Syntheses of O-glycosides of KDN / p25 (0033.jp2)
  12. 3.2 Mechanism of the glycosylation reaction / p29 (0037.jp2)
  13. PartII Chemistry of KDN glycal(2,6-anhydro-3-deoxy-D-glycero-D-galacto-non-2-enonic acid,KDN2en) / p32 (0040.jp2)
  14. Chapter1 Preparation of KDN2en / p33 (0041.jp2)
  15. 1.1 Preparation of KDN2en / p33 (0041.jp2)
  16. 1.2 Protections of the hydroxy groups in KDN2en / p35 (0043.jp2)
  17. Chapter2 Syntheses of 4-acylamino-4-deoxy-KDN2en and the scope of Ritter-type reaction / p38 (0046.jp2)
  18. 2.1 Syntheses of 4-acylamino-4-deoxy-KDN2en / p38 (0046.jp2)
  19. 2.2 Mechanism of the Ritter-type reaction / p43 (0051.jp2)
  20. 2.3 Syntheses of 4-amino-4-deoxy-KDN2en / p46 (0054.jp2)
  21. 2.4 Syntheses of 4-acylamino-4-deoxy-Neu5Ac2en / p48 (0056.jp2)
  22. Chapter3 Syntheses of sialic acids anologues / p51 (0059.jp2)
  23. 3.1 Syntheses of 4-acylamino-4-deoxy-KDN / p51 (0059.jp2)
  24. 3.2 Syntheses of 4-epi-acylamino-4-deoxy-KDN / p55 (0063.jp2)
  25. Chapter4 Synthesis of 4-oxo- and 4-hydroxyimino-KDN2en / p60 (0068.jp2)
  26. 4.1 Syntheses of 4-oxo-KDN2en / p60 (0068.jp2)
  27. 4.2 Syntheses of 4-hydroxyimino-KDN2en / p61 (0069.jp2)
  28. Chapter5 Syntheses of 2-deoxy-2-[化学式] and 2-Heq-KDN / p64 (0072.jp2)
  29. PartIII Syntheses of methyl 5-(tetra-acetoxybutyl)-2-furancarboxylate and α-(methoxycarbonyl)furfuryl amide / p68 (0076.jp2)
  30. Chapter1 Syntheses of methyl 5-(tetra-acetoxybutyl)-2-furancarboxylate / p68 (0076.jp2)
  31. 1.1 Syntheses of methyl 5-(tetra-acetoxybutyl)-2-furancarboxylate / p69 (0077.jp2)
  32. 1.2 Mechanism for the formation of methyl 5-(tetra-acetoxybutyl)-2-furancarboxylate / p71 (0079.jp2)
  33. Chapter2 Syntheses of α-(methoxycarbonyl)furfuryl amide / p74 (0082.jp2)
  34. 2.1 Syntheses of α-(methoxycarbonyl)furfuryl amide / p74 (0082.jp2)
  35. 2.2 Syntheses of polyhydroxyamino acids / p78 (0086.jp2)
  36. CONCLUSION / p79 (0087.jp2)
  37. EXPERIMENTAL PART / p81 (0089.jp2)
  38. I.1 Preparation of KDN / p82 (0090.jp2)
  39. I.2.1 Syntheses of N-glycosides of KDN / p83 (0091.jp2)
  40. I.2.2 Photocycloaddition of N-glycoside of KDN with 2,3-dimethyl-2-butene / p91 (0099.jp2)
  41. I.3.1 Syntheses of O-glycosides of KDN / p98 (0106.jp2)
  42. II.1.1 Preparation of KDN2en / p102 (0110.jp2)
  43. II.1.2 Protections of the hydroxy groups in KDN2en / p104 (0112.jp2)
  44. II.2.1 Syntheses of 4-acylamino-4-deoxy-KDN2en / p107 (0115.jp2)
  45. II.2.2 Mechanism of the Ritter-type reaction / p111 (0119.jp2)
  46. II.2.3 Syntheses of 4-amino-4-deoxy-KDN2en / p113 (0121.jp2)
  47. II.2.4 Syntheses of 4-acylamino-4-deoxy-Neu5Ac2en / p116 (0124.jp2)
  48. II.3 Syntheses of sialic acids anologues / p119 (0127.jp2)
  49. II.4 Syntheses of 4-oxo-and 4-hydroxyimino-KDN2en / p129 (0137.jp2)
  50. II.5 Syntheses of 2-deoxy-2-[化学式] and 2-Heq-KDN / p133 (0141.jp2)
  51. III.1 Syntheses of methyl 5-(tetra-acetoxybutyl)-2-furancarboxylate / p136 (0144.jp2)
  52. III.2.1 Syntheses of α-(methoxycarbonyl)furfuryl amide / p140 (0148.jp2)
  53. III.2.2 Syntheses of polyhydroxyamino acids / p143 (0151.jp2)
  54. REFERENCES and NOTES / p145 (0153.jp2)
  55. ACKNOWLEDGEMENTS / p151 (0159.jp2)
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各種コード

  • NII論文ID(NAID)
    500000150462
  • NII著者ID(NRID)
    • 8000001061310
  • DOI(NDL)
  • NDL書誌ID
    • 000000314776
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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