Stereochemistry and reactions of pentacoordinate organophosphorus compounds with Martin ligands マーチンリガンドを有する5配位有機リン化合物の立体化学と反応

博士論文

Contents Chapter 1.General Introduction 　A.General Introduction / p1 　B.References / p12 Chapter 2.Syntheses and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H(Apical) Phosphoranes Bearing a Hydroxy Group. 　A.Introduction / p16 　B.Results and Discussion / p18 　C.Experimental Section / p38 　D.References / p55 Chapter 3.First Characterization of 10-P-5 Spirophosphoranes with an Apical Carbon-Equatorial Oxygen ring. Kinetic Studies on Pseudorotation. 　A.Introduction / p57 　B.Results and Discussion / p60 　C.Experimental Section / p75 　D.References / p99 Chapter 4.Kinetic Studies of Thermal Cyclization Reactions of P-H(apical) Phosphoranes Bearing a Hydroxy Group. 　A.Introduction / p101 　B.Results and Discussion / p104 　C.Experimental Section / p115 　D.References / p136 Acknowledgements / p138 List of Publications / p139