Kinetics of isotopic exchange reactions involving thiosulfate and acetate intermediaries in hydrothermal systems チオサルフェイト及び酢酸中間体を媒体とする熱水系での同位体交換反応のキネティクス
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著者
書誌事項
- タイトル
-
Kinetics of isotopic exchange reactions involving thiosulfate and acetate intermediaries in hydrothermal systems
- タイトル別名
-
チオサルフェイト及び酢酸中間体を媒体とする熱水系での同位体交換反応のキネティクス
- 著者名
-
儲, 雪蕾
- 著者別名
-
チュー, シューレイ
- 学位授与大学
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東北大学
- 取得学位
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博士 (理学)
- 学位授与番号
-
乙第7260号
- 学位授与年月日
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1997-06-25
注記・抄録
博士論文
目次
- Contents / p1 (0004.jp2)
- Acknowledgments / p3 (0006.jp2)
- List of Tables / p4 (0007.jp2)
- List of Figures / p6 (0009.jp2)
- Abstract / p10 (0013.jp2)
- Introduction / p1 (0016.jp2)
- Chapter I:Kinetic Model of Isotope Exchange Reactions Involving Intra-and Intermolecular Reactions / p7 (0022.jp2)
- Abstract / p8 (0023.jp2)
- I.1 Introduction / p10 (0025.jp2)
- I.2 Rate law for the isotopic exchange reactions involving intra-and intermolecular exchanges / p13 (0028.jp2)
- I.3 Estimations of overall rate constants and equilibrium isotopic fractionation factors from experimental data / p22 (0037.jp2)
- I.4 Temporal changes in the isotopic compositions of species during intra-and intermolecular isotopic exchange / p26 (0041.jp2)
- I.5 Conclusions / p36 (0051.jp2)
- References / p38 (0053.jp2)
- Appendex I Derivation of solutions of simultaneous differential Eqns.(18),(19),and(20) / p41 (0056.jp2)
- Appendex II Derivation of relationship between 1-F and t / p44 (0059.jp2)
- Appendex III Summary of the used notations / p45 (0060.jp2)
- Chapter II:Kinetics of Sulfur Isotopic Exchange between Aqueous Sulfide and Thiosulfate at Hydrothermal Temperatures / p47 (0062.jp2)
- Abstract / p48 (0063.jp2)
- II.1 Introduction / p50 (0065.jp2)
- II.2 Principles of isotopic exchange kinetics involving intra-and inter-molecular reactions / p52 (0067.jp2)
- II.3 Kinetic and thermodynamic data on sulfur isotopic exchange reaction between aqueous sulfide and thiosulfate / p58 (0073.jp2)
- II.4 Mechanism of isotopic exchange between aqueous sulfide and thiosulfate / p76 (0091.jp2)
- II.5 Conclusions / p88 (0103.jp2)
- References / p91 (0106.jp2)
- Chapter III:Kinetic Investigations of Carbon Isotopic Exchange Reactions among Aqueous CO₂,CH₄,and Acetic Acid at 250℃ / p93 (0108.jp2)
- Abstract / p94 (0109.jp2)
- III.1 Introduction / p96 (0111.jp2)
- III.2 Experimental procedures / p100 (0115.jp2)
- III.3 Intramolecular carbon isotopic exchange in acetic acid / p119 (0134.jp2)
- III.4 Carbon isotopic exchange between CO₂ and CH₄ in acidic solutions / p120 (0135.jp2)
- III.5 Carbon isotopic exchange between CO₂ and acetic acid in solutions / p130 (0145.jp2)
- III.6 Conclusions / p140 (0155.jp2)
- References / p142 (0157.jp2)