Study on the synthesis and properties of hexaaryl[3]radialenes ヘキサアリール[3]ラジアレン類の合成と物性の研究

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著者

    • 榎本, 哲也 エノモト, テツヤ

書誌事項

タイトル

Study on the synthesis and properties of hexaaryl[3]radialenes

タイトル別名

ヘキサアリール[3]ラジアレン類の合成と物性の研究

著者名

榎本, 哲也

著者別名

エノモト, テツヤ

学位授与大学

大阪大学

取得学位

博士 (理学)

学位授与番号

甲第6175号

学位授与年月日

1998-03-25

注記・抄録

博士論文

目次

  1. Contents / (0003.jp2)
  2. Chapter I General introduction / p1 (0005.jp2)
  3. I-1 Introduction / p1 (0005.jp2)
  4. 1-2 The purpose of the present studies / p2 (0006.jp2)
  5. 1-3 Brief review of [3]radialenes / p4 (0007.jp2)
  6. 1-4 Contents of this thesis / p10 (0010.jp2)
  7. 1-5 References / p13 (0011.jp2)
  8. Chapter II Regioselective lithiation and functionalization of bis(2-thienyl)methane and related compounds / p16 (0013.jp2)
  9. II-1 Introduction / p16 (0013.jp2)
  10. II-2 Consideration on the acidity of substances relevant to DRL of bis(2-thienyl)methane / p17 (0013.jp2)
  11. II-3 Regioselective Cα-metalation of bis(2-thienyl)methane: A clean formation and spectral characterization of bis(2-thienyl)methyl anion / p18 (0014.jp2)
  12. II-4 Effects of bases,solvents,additives,and temperature upon the regioselective lithiation / p21 (0015.jp2)
  13. II-5 Rationalization of the doubly regioselective lithiation of bis(2-thienyl)methane / p22 (0016.jp2)
  14. II-6 Reactivity of bis(2-thienyl)methyl anion / p24 (0017.jp2)
  15. II-7 On the controversial results on the lithiation and formylation of bis(2-thienyl)methane / p25 (0017.jp2)
  16. II-8 Multiply regioselective lithiation of the related compounds / p25 (0017.jp2)
  17. II-9 Conclusion / p27 (0018.jp2)
  18. II-10 Experimental section / p28 (0019.jp2)
  19. II-11 References / p38 (0024.jp2)
  20. Chapter III Synthesis of hexaaryl[3]radialenes / p40 (0025.jp2)
  21. III-1 Introduction / p40 (0025.jp2)
  22. III-2 Acidity measurements of diarylmethanes / p41 (0025.jp2)
  23. III-3 Synthesis of hexaaryl[3]radialenes / p44 (0027.jp2)
  24. III-4 Synthesis of hexaphenyl[3]radialene / p45 (0027.jp2)
  25. III-5 Conclusion / p46 (0028.jp2)
  26. III-6 Experimental section / p47 (0028.jp2)
  27. III-7 References / p54 (0032.jp2)
  28. Chapter IV Structure and properties of hexaaryl[3]radialenes / p56 (0033.jp2)
  29. IV-1 Electronic spectra / p56 (0033.jp2)
  30. IV-2 NMR spectroscopy / p57 (0033.jp2)
  31. IV-3 Electrochemical property / p60 (0035.jp2)
  32. IV-4 Molecular structure of hexakis(4-cyanophenyl)[3]radialene / p62 (0036.jp2)
  33. IV-5 Experimental section / p64 (0037.jp2)
  34. IV-6 References / p65 (0037.jp2)
  35. Chapter V Functional group transformation of hexaaryl[3]radialenes / p66 (0038.jp2)
  36. V-1 Introduction / p66 (0038.jp2)
  37. V-2 Lithiation and functionalization of hexakis(2-thienyl)[3]radialene / p66 (0038.jp2)
  38. V-3 Generation of novel carbocation and carboanion containing [3]radialene moiety / p67 (0038.jp2)
  39. V-4 Pd-catalyzed coupling reaction of hexakis(4-iodophenyl)[3]radialene with terminal alkynes / p70 (0040.jp2)
  40. V-5 Pd-catalyzed coupling reaction of hexakis(4-bromophenyl)[3]radialene with diarylamine / p71 (0040.jp2)
  41. V-6 Water-soluble [3]radialene / p74 (0042.jp2)
  42. V-7 Synthesis of hexaphenyl[3]radialenes with benzyl functionality / p75 (0042.jp2)
  43. V-8 Conclusion / p76 (0043.jp2)
  44. V-9 Experimental section / p77 (0043.jp2)
  45. V-10 References / p86 (0048.jp2)
  46. Chapter VI Further transfomation of hexakis(4-ethynylphenyl)[3]radialene / p88 (0049.jp2)
  47. VI-1 Introduction / p88 (0049.jp2)
  48. VI-2 Lithiation and functionalization / p89 (0049.jp2)
  49. VI-3 Attempt of oxidative coupling(Eglinton coupling) / p90 (0050.jp2)
  50. VI-4 Cadiot-Chodkiewicz coupling / p92 (0051.jp2)
  51. VI-5 Pd-Catalyzed coupling reaction with bromoalkyne / p93 (0051.jp2)
  52. VI-6 Properties of ethynyl extended hexaphenyl[3]radialenes / p94 (0052.jp2)
  53. VI-7 Experimental section / p97 (0053.jp2)
  54. VI-8 References / p100 (0055.jp2)
  55. Appendix A Study on the acidity of 2(5) proton of thiophenes / p101 (0055.jp2)
  56. A-1 Introduction / p101 (0055.jp2)
  57. A-2 Reported pKa of thiophene / p103 (0056.jp2)
  58. A-3 Measurement of acidity of thiophenes / p103 (0056.jp2)
  59. A-4 Results and discussion / p104 (0057.jp2)
  60. A-5 Conclusion / p106 (0058.jp2)
  61. A-6 Experimental section / p107 (0058.jp2)
  62. A-7 References / p108 (0059.jp2)
  63. Appendix B Supplementary data of X-ray crystallography of hexakis(4-cyanophenyl)[3]radialene / p109 (0059.jp2)
  64. List of publications / p113 (0061.jp2)
  65. Acknowledgment / p114 (0062.jp2)
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  • NII論文ID(NAID)
    500000164635
  • NII著者ID(NRID)
    • 8000001157744
  • DOI(NDL)
  • 本文言語コード
    • und
  • NDL書誌ID
    • 000000328949
  • データ提供元
    • 機関リポジトリ
    • NDL ONLINE
    • NDLデジタルコレクション

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