Hydrogen adsorption characteristic and spillover mechanism on Pt/Al2O3 as studied by 1H and 2H solid-state NMR 固体1H及び2H NMRによるPt/Al2O3への水素の吸着特性とスピルオーバー機構の研究

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Author

    • 宮城, 慧 ミヤギ, ケイ

Bibliographic Information

Title

Hydrogen adsorption characteristic and spillover mechanism on Pt/Al2O3 as studied by 1H and 2H solid-state NMR

Other Title

固体1H及び2H NMRによるPt/Al2O3への水素の吸着特性とスピルオーバー機構の研究

Author

宮城, 慧

Author(Another name)

ミヤギ, ケイ

University

大阪大学

Types of degree

博士(理学)

Grant ID

甲第6547号

Degree year

1998-09-30

Note and Description

博士論文

Table of Contents

  1. Abstract / p1 (0003.jp2)
  2. Contents / (0005.jp2)
  3. Chapter1 Introduction / p1 (0006.jp2)
  4. 1.1 General remarks / p6 (0006.jp2)
  5. 1.2 Solid state NMR studies of hydrogen adsorbed on supported metal catalyst / p5 (0010.jp2)
  6. 1.3 Hydrogen spillover phenomenon / p8 (0013.jp2)
  7. 1.4 Purpose of the present work / p9 (0014.jp2)
  8. References to Chapter1 / p10 (0015.jp2)
  9. Chapter2 Characterization of the sample / p12 (0017.jp2)
  10. 2.1 Characterization by TEM and EDX / p12 (0017.jp2)
  11. 2.2 Powder X-ray diffraction / p15 (0020.jp2)
  12. 2.3 Hydrogen adsorption isotherm / p17 (0022.jp2)
  13. References to Chapter2 / p23 (0028.jp2)
  14. Chapter3 ¹H NMR of hydrogen adsorbed on Pt/Al₂O₃ / p24 (0029.jp2)
  15. 3.1 Experimental / p24 (0029.jp2)
  16. 3.2 Features of the ¹H NMR spectrum / p24 (0029.jp2)
  17. 3.3 Coverage dependence of the ¹H spectrum / p30 (0035.jp2)
  18. 3.4 Temperature dependence of the ¹H spectrum / p33 (0038.jp2)
  19. References to Chapter3 / p37 (0042.jp2)
  20. Chapter4 ²H NMR of deuterium adsorbed on Pt/Al₂O₃ / p38 (0043.jp2)
  21. 4.1 Experimental / p38 (0043.jp2)
  22. 4.2 Features of the ²H NMR spectrum / p38 (0043.jp2)
  23. 4.3 Temperature dependence of the ²H spectrum / p45 (0050.jp2)
  24. 4.4 The QCC value of ²H in the Pt-D species / p47 (0052.jp2)
  25. References to Chapter4 / p52 (0057.jp2)
  26. Chapter5 Hydrogen spillover on Pt/Al₂O₃ / p53 (0058.jp2)
  27. 5.1 Experimental / p53 (0058.jp2)
  28. 5.2 The variation of NMR spectrum due to hydrogen spillover process / p53 (0058.jp2)
  29. 5.3 The quantitative nature of the hydrogen spillover process / p54 (0059.jp2)
  30. References to Chapter5 / p61 (0066.jp2)
  31. Chapter6 Summary / p62 (0067.jp2)
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Codes

  • NII Article ID (NAID)
    500000171924
  • NII Author ID (NRID)
    • 8000000172198
  • DOI(NDL)
  • Text Lang
    • und
  • NDLBibID
    • 000000336238
  • Source
    • Institutional Repository
    • NDL ONLINE
    • NDL Digital Collections

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