Studies on pyridinyl-based high-spin molecules ピリジニルを基盤とする高スピン分子の研究
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Bibliographic Information
- Title
-
Studies on pyridinyl-based high-spin molecules
- Other Title
-
ピリジニルを基盤とする高スピン分子の研究
- Author
-
松本, 幸三
- Author(Another name)
-
マツモト, コウゾウ
- University
-
大阪大学
- Types of degree
-
博士(理学)
- Grant ID
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甲第6550号
- Degree year
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1998-09-30
Note and Description
博士論文
Table of Contents
- Contents / (0003.jp2)
- Chapter 1 General Introduction / p1 (0005.jp2)
- 1-1.Introduction / p1 (0005.jp2)
- 1-2.Brief review of pyridinyl radicals / p3 (0006.jp2)
- 1-3.Theory of spin alignment in high-spin molecules / p7 (0008.jp2)
- 1-4.Purpose of this study and contents of this thesis / p12 (0011.jp2)
- 1-5.References / p16 (0013.jp2)
- Chapter 2.Preparations and properties of 1,3-bis(1-methyl-2,6-diphenyl-pyridinyl-4-yl)benzene,1,3,5-tris(1-methyl-2,6-diphenylpyridinyl-4-yl)benzene,and their analogues / p19 (0014.jp2)
- 2-1.Introduction / p19 (0014.jp2)
- 2-2.Preparation and characterization of 1-methyl-2,4,6-triphenylpyridinyl radical(16) / p20 (0015.jp2)
- 2-3.Preparation and characterization of 1,3-bis(1-methyl-2,6-diphenyl-pyridinyl-4-yl)benzene(1) and 1,3,5-tris(1-methyl-2,6-diphenylpyridinyl-4-yl)benzene(2) / p24 (0017.jp2)
- 2-4.Preparations and characterization of 1,4-bis(1-methyl-2,6-diphenylpyridinyl-4-yl)benzene(24) / p35 (0022.jp2)
- 2-5.Preparations and characterization of bis-pyridinyl radicals linked with methyl substituted benzene / p39 (0024.jp2)
- 2-6.Preparation and characterization of 1,8-bis(1-methyl-2,6-diphenylpyridinyl-4-yl)anthracene / p48 (0029.jp2)
- 2-7.Experimental section / p55 (0032.jp2)
- 2-8.References / p70 (0040.jp2)
- Chapter 3.Preparations and properties of 1,3- and 1,4-bis(2,4,6-triphenylpyridinyl-1-yl)benzene and 1,5-bis 2,4,6-triphenylpyridinyl-1-yl)naphthalene / p73 (0041.jp2)
- 3-1.Introduction / p73 (0041.jp2)
- 3-2.Syntheses of 1,3- and 1,4-bis(2,4,6-triphenylpyridinium-1-yl)benzene bis(tetrafluoroborate) 〔6²⁺･2(BF₄⁻)and 7²⁺･2(BF₄⁻)〕 and 1,5-bis(2,4,6-triphenylpyridinium-1-yl)naphthalene bis(tetrafluoroborate) 〔8²⁺･2(BF₄⁻)〕 / p75 (0042.jp2)
- 3-3.¹H and ¹³C chemical shifts of bispyridinium salts 6²⁺･2(BF₄⁻) and 7²⁺･2(BF₄⁻) / p76 (0043.jp2)
- 3-4.Reduction potentials and absorption maxima in electronic spectrum of bispyridinium salts 6²⁺･2(BF₄⁻), 7²⁺･2(BF₄⁻), and 8²⁺･2(BF₄⁻) / p77 (0043.jp2)
- 3-5.Electronic spectrum of 1,2,4,6-tetraphenylpyridinyl radical(38) / p78 (0044.jp2)
- 3-6.Electronic spectra of bis-pyridinyl radicals 6,7,and 8 / p80 (0045.jp2)
- 3-7.ESR spectra of 1,3- and 1,4-bis(2,4,6-triphenylpyridinyl-1-yl)benzene (6 and 7) and 1,5-bis(2,4,6-triphenylpyridinium-1-yl)naphthalene(8) / p83 (0046.jp2)
- 3-8.Summary / p87 (0048.jp2)
- 3-9.Experimental section / p89 (0049.jp2)
- Chapter 4.Preparation and exchange interaction of bis(2,4,6-triphenylpyridinyl-1-yl)diradicals linked with polymethylene and 1,4-trans-cyclohexanediyl spacer / p91 (0050.jp2)
- 4-1.Introduction / p91 (0050.jp2)
- 4-2.Preparations of 1,1'-(1,n-alkanediyl)bis(2,4,6-triphenylpyridinium-1-yl) bis(tetrafluoroborate) 〔9²⁺･2(BF₄⁻) to 14²⁺･2(BF₄⁻)〕 / p93 (0051.jp2)
- 4-3.¹H and ¹³C chemical shifts of bispyridinium salts 9²⁺･2(BF₄⁻)-14²⁺･2(BF₄⁻) / p93 (0051.jp2)
- 4-4.Reduction potentials and absorption maxima in electronic spectrum of bispyridinium salts 9²⁺･2(BF₄⁻)-14²⁺･2(BF₄⁻) / p96 (0053.jp2)
- 4-5.Electronic spectra obtained by reduction of bispyridinium salts 9²⁺･2(BF₄⁻)-14²⁺･2(BF₄⁻) / p97 (0053.jp2)
- 4-6.ESR spectra of diradicals 9-14 / p98 (0054.jp2)
- 4-7.Preparation and characterization of 1,4-trans-bis(2,4,6-triphenylpyridinyl-yl)cyclohexane(15) / p103 (0056.jp2)
- 4-8.Summary / p105 (0057.jp2)
- 4-9.Experimental section / p107 (0058.jp2)
- 4-10.References / p110 (0060.jp2)
- Conclusion / p111 (0060.jp2)
- List of publication / p113 (0061.jp2)
- Acknowledgement / p114 (0062.jp2)
