Study on redox properties of some biomimetic metal complexs : oxo-bridged dimers and metal-phenolato monomers 生体関連金属錯体の酸化還元挙動に関する研究 : オキソ架橋復核錯体とフェノラト単核錯体

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著者

    • 菊地, 晶裕 キクチ, アキヒロ

書誌事項

タイトル

Study on redox properties of some biomimetic metal complexs : oxo-bridged dimers and metal-phenolato monomers

タイトル別名

生体関連金属錯体の酸化還元挙動に関する研究 : オキソ架橋復核錯体とフェノラト単核錯体

著者名

菊地, 晶裕

著者別名

キクチ, アキヒロ

学位授与大学

北海道大学

取得学位

博士(理学)

学位授与番号

甲第4623号

学位授与年月日

1999-03-25

注記・抄録

博士論文

目次

  1. Contents / p4 (0004.jp2)
  2. Part 1.Proton-Coupled Electron Transfer Reactions of Some Oxo-Bridged Dinuclear Ruthenium Complexes / p1 (0009.jp2)
  3. Chapter 1 Introduction / p3 (0010.jp2)
  4. 1-1 Proton-Coupled Electron Transfer Reactions / p4 (0011.jp2)
  5. 1-2 Proton-Coupled Electron Transfer Reactions of Oxo-Bridged Complexes / p5 (0011.jp2)
  6. 1-3 Purpose of This Study / p8 (0013.jp2)
  7. Chapter 2 Experimental Section / p15 (0016.jp2)
  8. 2-1 Physical Measurements / p16 (0017.jp2)
  9. 2-2 Materials / p17 (0017.jp2)
  10. 2-3 Preparation of the Complexes / p17 (0017.jp2)
  11. Chapter 3 Redox Chemistry in Aqueous Medium / p31 (0024.jp2)
  12. 3-1 Introduction / p32 (0025.jp2)
  13. 3-2 Results / p32 (0025.jp2)
  14. 3-3 Discussion / p33 (0025.jp2)
  15. Chapter 4 Redox Chemistry in Acetonitrile / p37 (0027.jp2)
  16. 4-1 Introduction / p38 (0028.jp2)
  17. 4-2 Results / p38 (0028.jp2)
  18. 4-3 Discussion / p41 (0029.jp2)
  19. Chapter 5 Estimation of the pKa Value of the Oxo-Bridge at Different Oxidation State / p55 (0036.jp2)
  20. 5-1 Introduction / p56 (0037.jp2)
  21. 5-2 Discussion / p56 (0037.jp2)
  22. Chapter 6 Detailed Mechanism of Proton-Coupled Electron Transfer Reaction in Acetonitrile / p60 (0039.jp2)
  23. 6-1 Introduction / p61 (0039.jp2)
  24. 6-2 Results and Discussion / p61 (0039.jp2)
  25. Chapter 7 Proton-Exchange Rate Constants / p69 (0043.jp2)
  26. 7-1 Introduction / p70 (0044.jp2)
  27. 7-2 Results and Discussion / p70 (0044.jp2)
  28. Chapter 8 Proton-Coupled Electron Transfer Reaction of the Complex Having Proton Source as a Ligand / p78 (0048.jp2)
  29. 8-1 Introduction / p79 (0048.jp2)
  30. 8-2 Results and Discussion / p79 (0048.jp2)
  31. Chapter 9 Application of the New Approach to Another Systems / p87 (0052.jp2)
  32. 9-1 Introduction / p88 (0053.jp2)
  33. 9-2 Results and Discussion / p88 (0053.jp2)
  34. Chapter 10 Conclusion / p92 (0055.jp2)
  35. References for Part 1 / p95 (0056.jp2)
  36. Part 2 X-ray Absorption Fine Structure Study of Some Oxo-Bridged Ruthenium Complexes / p100 (0059.jp2)
  37. Chapter 1 Introduction / p102 (0060.jp2)
  38. 1-1 Oxo-Bridged Dinuclear Complexes / p103 (0060.jp2)
  39. 1-2 Oxo-Bridged Trinuclear Complexes / p105 (0061.jp2)
  40. Chapter 2 XAFS Study of Different Oxidation States of Oxo-And Hydroxo-Bridged Ruthenium Dimers in Acetonitrile Solution / p108 (0063.jp2)
  41. 2-1 Introduction / p109 (0063.jp2)
  42. 2-2 Experimental Section / p109 (0063.jp2)
  43. 2-3 Results and Discussion / p111 (0064.jp2)
  44. Chapter 3 Determination of the Structure of [Ru₂M(μ-O)(μ-CH₃COO)₆(pyridine)₃]ⁿ⁺ by XAFS Spectroscopy / p127 (0072.jp2)
  45. 3-1 Introduction / p128 (0073.jp2)
  46. 3-2 Experimental Section / p128 (0073.jp2)
  47. 3-3 Results and Discussion / p130 (0074.jp2)
  48. Chapter 4 Conclusion / p156 (0087.jp2)
  49. Supplemental Data / p158 (0088.jp2)
  50. References for Part 2 / p163 (0090.jp2)
  51. Part 3.Ligand-centered Oxidation in Metal-Phenolate Complexes:Characterization of Phenoxyl Radical Complexes / p168 (0093.jp2)
  52. Chapter 1 Introduction / p170 (0094.jp2)
  53. 1-1 Metalloenzymes Utilizing Tyrosyl Radicals / p171 (0094.jp2)
  54. 1-2 Oxidation of Phenols / p173 (0095.jp2)
  55. 1-3 Metal Complexes with Phenoxyl Radicals / p175 (0096.jp2)
  56. 1-4 The Purpose of This Study / p177 (0097.jp2)
  57. Chapter 2 Preparation of the Ligand / p184 (0101.jp2)
  58. 2-1 Introduction / p185 (0101.jp2)
  59. 2-2 Preparation of the ligand / p185 (0101.jp2)
  60. 2-3 Properties of the Ligands / p189 (0103.jp2)
  61. 2-4 Oxidation of the Ligand / p190 (0104.jp2)
  62. Chapter 3 Cobalt Complexes / p207 (0112.jp2)
  63. 3-1 Introduction / p208 (0113.jp2)
  64. 3-2 Experimental Section / p209 (0113.jp2)
  65. 3-3 Results and Discussion / p213 (0115.jp2)
  66. 3-4 Conclusion / p221 (0119.jp2)
  67. Chapter 4 Chromium and Nickel Complexes / p246 (0132.jp2)
  68. 4-1 Introduction / p247 (0132.jp2)
  69. 4-2 Experimental Section / p247 (0132.jp2)
  70. 4-3 Results and Discussion / p251 (0134.jp2)
  71. 4-4 Conclusion / p256 (0137.jp2)
  72. Chapter 5 Iron and Manganese Complexes / p276 (0147.jp2)
  73. 5-1 Introduction / p277 (0147.jp2)
  74. 5-2 Experimental Section / p277 (0147.jp2)
  75. 5-3 Results and Discussion / p279 (0148.jp2)
  76. 5-4 Conclusion / p283 (0150.jp2)
  77. Chapter 6 Cadmium,Mercury and Molybdenum Complexes / p299 (0158.jp2)
  78. 6-1 Introduction / p300 (0159.jp2)
  79. 6-2 Experimental Section / p301 (0159.jp2)
  80. 6-3 Results and Discussion / p304 (0161.jp2)
  81. 6-4 Conclusion / p312 (0165.jp2)
  82. Chapter 7 Conclusion / p338 (0178.jp2)
  83. References for Part 3 / p341 (0179.jp2)
  84. Summary and Prospective / p348 (0183.jp2)
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各種コード

  • NII論文ID(NAID)
    500000172181
  • NII著者ID(NRID)
    • 8000000172456
  • DOI(NDL)
  • NDL書誌ID
    • 000000336495
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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