A new class of polymers: starburst-dendritic

• Tomalia D. A.

  The Analytical Laboratory, Dow Chemical U.S.A.

• Baker H.

  Functional Polymers/Process Dow Chemical U.S.A.

• Dewald J.

  Functional Polymers/Process Dow Chemical U.S.A.

• Hall M.

  Functional Polymers/Process Dow Chemical U.S.A.

• Kallos G.

  Functional Polymers/Process Dow Chemical U.S.A.

• Martin S.

  Functional Polymers/Process Dow Chemical U.S.A.

• Roeck J.

  Functional Polymers/Process Dow Chemical U.S.A.

• Ryder J.

  Functional Polymers/Process Dow Chemical U.S.A.

• Smith P.

  Functional Polymers/Process Dow Chemical U.S.A.

書誌事項

タイトル別名

• A new class of polymers: Starburst-dendritic macromolecules.
• A new class of polymers: starburt-dendritic macromolecules

抄録

This paper describes the first synthesis of a new class of topological macromolecules which we refer to as “starburst polymers.” The fundamental building blocks to this new polymer class are referred to as “dendrimers.” These dendrimers differ from classical monomers/oligomers by their extraordinary symmetry, high branching and maximized (telechelic) terminal functionality density. The dendrimers possess “reactive end groups” which allow (a) controlled moelcular weight building (monodispersity), (b) controlled branching (topology), and (c) versatility in design and modification of the terminal end groups. Dendrimer synthesis is accomplished by a variety of strategies involving “time sequenced propagation” techniques. The resulting dendrimers grow in a geometrically progressive fashion as shown: Chemically bridging these dendrimers leads to the new class of macromolecules—”starburst polymers” (e.g., (A)_n, (B)_n, or (C)_n).

収録刊行物

• Polymer Journal

  Polymer Journal 17 (1), 117-132, 1985

  The Society of Polymer Science, Japan

キーワード

• Starburst Polymers
• Straburst Oligomers
• Dendrimers
• Topological Macromers
• Polyamidoamines
• Dendritic Macromolecules Organic Clusters

詳細情報

• CRID: 1390001206290082304
• NII論文ID: 130004428591
• NII論文ID: 80002327729
• DOI: 10.1295/polymj.17.117
• COI: 1:CAS:528:DyaL2MXhsV2ru70%3D
• ISSN: 13490540
• ISSN: 00323896
• ISSN: http://id.crossref.org/issn/00323896
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可