Generation of diamond nuclei by electric field in plasma chemical vapor deposition

  • S. Yugo
    University of Electro-Communications, Choufu-shi, 182 Tokyo, Japan
  • T. Kanai
    University of Electro-Communications, Choufu-shi, 182 Tokyo, Japan
  • T. Kimura
    University of Electro-Communications, Choufu-shi, 182 Tokyo, Japan
  • T. Muto
    University of Electro-Communications, Choufu-shi, 182 Tokyo, Japan

抄録

<jats:p>Generation of diamond nuclei has been realized on a silicon mirror surface in plasma chemical vapor deposition. Prior to the normal diamond growth process, a predeposition process of several minutes duration was introduced in which a high methane fraction in the feed gas was used and in which a negative bias voltage was applied to the substrate. This resulted in an enormous enhancement of the generation of diamond nuclei. For the onset of diamond nucleation the minimum voltage was −70 V and the minimum methane fraction in the methane-hydrogen feed gas was 5%. Density of a diamond nuclei as high as 1010/cm2 was attained with this method.</jats:p>

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