Synthesis and control of conductivity of ultraviolet transmitting β-Ga2O3 single crystals

  • Naoyuki Ueda
    Institute for Molecular Science, Myodaiji, Okazaki 444, Japan
  • Hideo Hosono
    Institute for Molecular Science, Myodaiji, Okazaki 444, Japan
  • Ryuta Waseda
    Materials and Structures Laboratory, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama 226, Japan
  • Hiroshi Kawazoe
    Materials and Structures Laboratory, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama 226, Japan

抄録

<jats:p>β- Ga 2 O 3 single crystals were grown by the floating zone method and their conductivity along the b axis was controlled from &lt;10−9 to 38 Ω−1 cm−1 by changing the growth atmosphere. By using feed rods doped with Sn, the grown crystal became highly conductive even under oxidative atmosphere. The optical transmission spectra showed that the β-Ga2O3 single crystal with 0.32 mm was transparent in the visible and ultraviolet region, with 20% transmittance at the fourth-harmonic wave of the Nd:YAG laser (266 nm). The band-gap widening was observed with the increasing of the carrier concentration. It is expected that the light of the KrF laser can be transmitted in the heavily doped β-Ga2O3.</jats:p>

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