Facile and general method for preparation of (<i>E</i>)‐4‐hydroxy‐2‐alkenals

DOI Web Site 被引用文献4件
  • Kazuhiro Sugamoto
    Department of Materials Science, Faculty of Engineering Miyazaki University Gakuen‐Kibanadai Miyazaki 889‐21 Japan
  • Yoh‐ichi Matsushita
    Department of Materials Science, Faculty of Engineering Miyazaki University Gakuen‐Kibanadai Miyazaki 889‐21 Japan
  • Takanao Matsui
    Department of Materials Science, Faculty of Engineering Miyazaki University Gakuen‐Kibanadai Miyazaki 889‐21 Japan

抄録

<jats:title>Abstract</jats:title><jats:p>A facile one‐pot synthesis of (<jats:italic>E</jats:italic>)‐4‐hydroxy‐2‐alkenals such as (<jats:italic>E</jats:italic>)‐4‐hydroxy‐2‐nonenal, (<jats:italic>E</jats:italic>)‐4‐hydroxy‐2‐heptenal, and (<jats:italic>E</jats:italic>)‐4‐hydroxy‐2‐hexenal was achieved from the corresponding (2<jats:italic>E</jats:italic>,4<jats:italic>E</jats:italic>)‐2,4‐alkadienals by reduction‐oxygenation with molecular oxygen and triethylsilane in the presence of cobalt(II) porphyrin as a catalyst followed by treatment with trimethylphosphite.</jats:p>

収録刊行物

  • Lipids

    Lipids 32 (8), 903-905, 1997-08

    Wiley

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