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vol. 6 : 2000 ISBN 9780762305575
内容説明
In this volume, inorganic, organic, and bioorganic chemistry are represented in contributions from around the world. Pioneering work in self-assembled structures organized by the use of transition metals is described in chapter 1, followed by details of extensive studies of self-assembled structures formed from various biomolecules in chapter 2. The next two chapters describe the formation of spherical molecular containers and their understanding of such structures based on Platonic and Archimedean solids, and the fascinating family of synthetic peptide receptors and the interactions that can be explored using these host molecules. In chapter 5 a mixture of computational chemistry, drug design, and synthetic organic and inorganic chemistry in the development of superoxide dismutase mimics is described. The final two chapters discuss the bioorganic and supramolecular principles required for the design of synthetic artificial enzymes, and the supramolecular self-assembly and its possible role in the origin of life.
It is hoped that this broad, international view of supramolecular chemistry and the many directions it leads will be of interest to those already in the field. It is also hoped that those outside the field may see extensions of their own work that will bring them into it.
目次
List of contributors. Preface. Molecular self-assemblies through coordination: macrocycles, catenanes, cages, and tubes. Chiral self-assembled structures from biomolecules and synthetic analogues. Spherical molecular containers: from discovery to designod). Synthetic peptide receptors: noncovalent interactions involving peptides. Rational design of synthetic enzymes and their potential utility as human pharmaceuticals: development of manganese(II)-based superoxide dismutase mimics. Designing active sites of synthetic artificial enzymes. The relevance of supramolecular chemistry for the origin of life. Index.
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vol. 7 ISBN 9780762306787
内容説明
This volume presents a variety of articles that encompass the broad scope of supramolecular chemistry. Reusch's chapter covers biological channel compounds, while the work of Hall and Kirkovits looks into their synthetic counterparts. Metal ion sensors, calixarenes and "crystal engineering" are described by pioneers in these fields. This work, whilst current and authoritative, shows us that much remains to be undertaken and understood. It is hoped that this volume will be of interest to those who wish to fill these gaps; scientists already in the field and those who may see extensions of their own work that will bring them into it.
目次
Supramolecular assemblies in natural and artificial ion channels (G.J. Kirkovits, C.D. Hall). Ion recognition and transport by Poly-(R)-3-hyroxybutanoates and inorganic polyphosphates (R.M. Reusch). Functionalized macrocyclic ligands as sensory molecules for metal ions (G. Xue et al.). Chirality in calixarenes and calixarene assemblies (M. Vysotsky et al.). From molecules to crystals: supramolecular synthesis of solids (B. Moulton, M.J. Zaworotko). Index.
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vol. 1 : 1990 ISBN 9781559381819
目次
Introduction to the series: an editor's foreword (A. Padwa). Preface (G.W. Gokel). Hydrogen binding in biological and artificial molecular recognition (A.D. Hamilton). Synthetic ditopic receptors (I.O. Sutherland). Molecular recognition by macrocycles having a three-dimensionally extended hydrophobic cavity (Y. Murakami et al.). Pre-organization and molecular recognition in the formation and reactions of binuclear metal complexes (A.E. Martell). Index.
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vol. 2 : 1992 ISBN 9781559383295
内容説明
Preface (G.W. Gokel). Cyclodextrin complexation of amphiphilic compounds (A. Kaifer). Monolayer Lipid Membranes (MLMs) from bola- amphilhiles (J.-H. Fuhrhopa, R. Bach). Accumulation of unit-binding sites: hydrogen bonding fixation in multi-functional polar organic molecules (Y. Aoyama). Thermal fluctuations of membranes (M.D.
目次
Preface (G.W. Gokel). Cyclodextrin complexation of amphiphilic compounds (A. Kaifer). Monolayer Lipid Membranes (MLMs) from bola-amphilhiles (J.-H. Fuhrhopa, R. Bach). Accumulation of unit-binding sites: hydrogen bonding fixation in multi-functional polar organic molecules (Y. Aoyama). Thermal fluctuations of membranes (M.D. Mitov et al.). Molecular recognition in the solid state (F. Toda). Photoactivation of metal complexes on porous vycor glass (H.D. Gafney). Index.
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vol. 3 : 1993 ISBN 9781559385466
内容説明
Part of a series which presents reports of efforts in all areas of supramolecular science, this volume discusses such topics as: cryptophanes; inclusion polymerization in steroidal canal complexes; and functional tetraazamacrocycles; among other topics.
目次
- Cryptophanes - receptors for tetrahedral molecules, Andre Collett, Jean-Pierre Dutasta and Benedict Lozach
- inclusion polymerization in steroidal canal complexes, Kiichi Takemoto and Mikiji Miyata
- functionalized tetraazamacrocycles - ligands with many aspects, Thomas A. Kaden
- calixarenes as the third supramolecular host, Seiji Shinkai
- fluorescent chemosensors for metal and non-metal ions in aqueous solutions based on the chief paradigm, Anthony W. Czarnik.
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vol. 4 : 1997 ISBN 9781559387941
内容説明
Part of a series which presents reports of efforts in all areas of supramolecular science, this volume discusses a variety of topics in the field.
目次
Preface (G.W. Gokel). Supramolecular photoionic devices: photoinduced electron transfer (PET) systems with switchable luminescence output (A. Prasanna de Silva et al.). Molecular recognition in chemistry and biology as viewed from enthalpy-entropy compensation effect: global understanding of supramolecular interactions (Y. Inoue, T. Wada). Anion binding by sapphyrins (J.L. Sessler et al.). Avidin-biotin supramolecular complexation for biosensor applications (J. Anzai, Y. Osa). Artificial ion channels (Y. Kobuke). Chemical sensing based on membranes with supramolecular functions of biomimetic and biological origin (K. Odashima et al.). Supramolecular anion receptors (K.Travis et al.). Index.
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