書誌事項

Compounds with sulfur of oxidation number II

authors, Norbert Baumann, Hans-Jürgen Fachmann, Reimund Jotter ; editors, Norbert Baumann ...[et al.] ; chief editor, Alfons Kubny

(Gmelin handbook of inorganic chemistry / prepared and issued by Gmelin-Institut für Anorganische Chemie der Max-Planck-Gesellschaft zur Förderung der Wissenschaften ; director, Ekkehard Fluck, system no. 9 . S, sulfur-nitrogen compounds)

Springer, 1993-

  • pt. 9 : gw
  • pt. 9 : us
  • pt. 10a : gw
  • pt. 10a : us
  • pt. 10b : gw
  • pt. 10b : us
  • pt. 11 : gw
  • pt. 11 : us

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注記

Literature closing date: 1991, In many cases more recent data have beeen considered

内容説明・目次

巻冊次

pt. 9 : gw ISBN 9783540936640

内容説明

The present volume of the series Sulfur-Nitrogen Compounds describes sulfur(II)-nitrogen and sulfur(II)-nitrogen-element ring systems. The compounds are arranged according to ring size: The three-atom ring S(NR)2 and the five-atom ring S3(NR)2-3,5, where R = C2F5, CF2Cl, are prepared by photolyzing mixtures of RN=NR and S2Cl2. The six-atom rings S2(NR)4-2,3,5,6, S4(NR)2-3,6, S4(NR)2-5,6, and S4(NR)2-4,6, where R = organyl, can be synthesized from SxCl2(x = 1 to 3) and amines, hydrazines, or diimines. The eight-atom rings S7NH, S6(NH)2, and S5(NH)3 are obtained by reacting S2Cl2 and NH3 in DMF. The well-known ring S4(NH)4-2,4,6,8 was first prepared in 1908 by reduction of S4N4 with SnCl2.2 H2O. Numerous organic and inorganic derivatives of these eight-atom S-N rings including the anion S7N-, adducts, polymers, and metal complexes are also dealt with. A large portion of the volume is devoted to sulfur(II)-nitrogen-element ring systems. The S-N-C rings possess biological activity.
巻冊次

pt. 10a : gw ISBN 9783540937012

内容説明

This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by 2 + 4 cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only S=N=S +AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium salts. Thiohydroxylamine, HSNH2, has been detected in the gas phase. Numerous examples of N, N-diorganyl-amino-halogeno-sulfanes (XSNR2, X = F, Cl, Br, I; R = organyl) and salts of the cation (XS)2N+ (X = Cl, Br) are known. N, N-Diorganyl-amino-chloro-sulfanes are important synthetic reagents.

目次

1 Sulfur Imide and Derivatives.- 2 Disulfur Nitride, Nitrogen Disulfide, SNS.- 3 Dithionitrous Acid and Derivatives.- 4 Salts of the Dithionitryl Ion (1+), [S=N=S]+.- 5 Dinitrogen Sulfide, SNN.- 6 N-Thionitroso-diorganylamines and Derivatives.- 7 Thiohydroxylamine and Derivatives.- 8 Thiooximes and Derivatives.- 9 Thiofulminic Acid and Derivatives.- 10 Isohypothiocyanous Acid Ion (1?), OCNS?.- 11 Thionitrous Acid and Derivatives.- 12 Sulfur Amide Halogenides and Derivatives.- 13 Sulfur Amide Hydroxide Derivatives, N,N-Substituted Amino-organyloxy-sulfanes.- 14 S-Phosphorus-Substituted Thiohydroxylamines and Derivatives.- Physical Constants and Conversion Factors.
巻冊次

pt. 10b : gw ISBN 9783540937074

内容説明

This volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N, N, N', N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N, N, N', N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z 2. Reactions of R2NSNR2 with isocyanate and isothiocyanate, R'N=C=Y (Y = O, S), produce R2NSN(R')C(Y)NR2. The biological activity of diaminosulfanes with the appropriate substituents (e.g., R-OC(O), R = 2,2-dimethyl-2,3-dihydro-7-yl-benzofuran) has been ex
巻冊次

pt. 11 : gw ISBN 9783540937371

内容説明

The volume continues the description of acyclic sulfur - nitrogen compounds with sulfur having the oxidation number II and covers amino-di- and aminopolysulfanes as well as diamino-di- and diamino-polysulfanes. Numerous examples of the class of diamino-disulfanes and their interesting chemical properties are described: N, N'-disulfanediyl-bis(N-heterocycles), for instance, undergo S-S bond scission in a thermal or photochemical radical - dimer equilibrium or react with acetylenes to give thiophenes, and N, N'disulfanediyl-bis(phthalimide) is a sulfur transfer reagent for organic synthesis. The volume completes the series on sulfur - nitrogen compounds which is a unique and comprehensive source of information for this field in chemistr

目次

Acyclic Sulfur(II)-Nitrogen Compounds and Derivatives.- 1 Sulfur Imide and Derivatives.- 2 Disulfur Nitride, Nitrogen Disulfide, SNS.- 3 Dithionitrous Acid and Derivatives.- 4 Salts of the Dithionitryl Ion (1+), [S=N=S]+.- 5 Dinitrogen Sulfide, SNN.- 6 N-Thionitroso-diorganylamines and Derivatives.- 7 Thiohydroxylamine and Derivatives.- 8 Thiooximes and Derivatives.- 9 Thiofulminic Acid and Derivatives.- 10 Isohypothiocyanous Acid Ion (1?), OCNS?.- 11 Thionitrous Acid and Derivatives.- 12 Sulfur Amide Halogenides and Derivatives.- 13 Sulfur Amide Hydroxide Derivatives, N,N-Substituted Amino-organyloxy-sulfanes.- 14 S-Phosphorus-Substituted Thiohydroxylamines and Derivatives.

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  • Gmelin handbook of inorganic chemistry

    prepared and issued by Gmelin-Institut für Anorganische Chemie der Max-Planck-Gesellschaft zur Förderung der Wissenschaften ; director, Ekkehard Fluck

    Springer-Verlag 1975- 8th ed. = 8., völlig neu bearbeitete Aufl. / founded by Leopold Gmelin ; 8th edition begun under the auspices of the Deutsche Chemische Gesellschaft by R.J. Meyer ; continued by E.H.E. Pietsch and A. Kotowski, and by Margot Becke-Goehring

    Formula index. 1st suppl. v. 1 : gw , Formula index. 1st suppl. v. 1 : us , Formula index. 1st suppl. v. 2 : gw , Formula index. 1st suppl. v. 2 : us , Formula index. 1st suppl. v. 3 : gw , Formula index. 1st suppl. v. 3 : us , Formula index. 1st suppl. v. 4 : gw , Formula index. 1st suppl. v. 4 : us , Formula index. 1st suppl. v. 5 : gw , Formula index. 1st suppl. v. 5 : us , Formula index. 1st suppl. v. 6 : gw , Formula index. 1st suppl. v. 6 : us , Formula index. 1st suppl. v. 7 : gw , Formula index. 1st suppl. v. 7 : us , Formula index. 1st suppl. v. 8 : gw , Formula index. 1st suppl. v. 8 : us , Formula index. 2nd suppl. v. 1 : gw , Formula index. 2nd suppl. v. 1 : us , Formula index. 2nd suppl. v. 2 : gw , Formula index. 2nd suppl. v. 2 : us , Formula index. 2nd suppl. v. 3 : gw , Formula index. 2nd suppl. v. 3 : us , Formula index. 2nd suppl. v. 4 : gw , Formula index. 2nd suppl. v. 4 : us , Formula index. 2nd suppl. v. 5 : gw , Formula index. 2nd suppl. v. 5 : us , Formula index. 2nd suppl. v. 6 : gw , Formula index. 2nd suppl. v. 6 : us , Formula index. 2nd suppl. v. 7 : gw , Formula index. 2nd suppl. v. 7 : us , Formula index. 2nd suppl. v. 8 : gw , Formula index. 2nd suppl. v. 8 : us , Formula index. 2nd suppl. v. 9 : gw , Formula index. 2nd suppl. v. 9 : us , Formula index. 2nd suppl. v. 10 : gw , Formula index. 2nd suppl. v. 10 : us

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詳細情報

  • NII書誌ID(NCID)
    BA20875159
  • ISBN
    • 3540936645
    • 0387936645
    • 3540937013
    • 0387937013
    • 3540937072
    • 0387937072
    • 3540937374
    • 0387937374
  • 出版国コード
    gw
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Berlin ; Tokyo
  • ページ数/冊数
    v.
  • 大きさ
    26 cm
  • 親書誌ID
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