Stereospecific polymerization and stereoregular polymers : Milan. Italy June 8-12, 2003

Author(s)

    • EUPOC
    • Giarrusso, A.
    • Ricci, G.
    • Tritto, I.

Bibliographic Information

Stereospecific polymerization and stereoregular polymers : Milan. Italy June 8-12, 2003

symposum editor: A. Giarrusso, G. Ricci, I. Tritto

(Macromolecular symposia, 213)

WILEY-VCH, c2004

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Includes bibliographical references and index

Description and Table of Contents

Description

EUPOC 2003, European Polymer Conference on "Stereo specific Polymerization and Stereoregular Polymers" was held on June 8-12, 2003 in Milan, Italy. The symposium was organized to celebrate the centenary of the birth of Giulio Natta, who shared the 1963 Nobel Prize in Chemistry with Karl Ziegler. The symposium provided a forum to discuss: new results and perspectives on novel catalysts; and synthesis, structure, characterization, and applications of polyolefins. The symposium covered the following topics: traditional catalysts; metallocene catalysts; more recent catalysts; molecular modeling; polymerization mechanisms; structural aspects and properties of stereoregular polymers; and, new products and processes. This volume of Macromolecular Symposia is a collection of some of the lectures presented at the symposium and the opening lecture profiling Giulio Natta as a scientist and as a man.

Table of Contents

  • Preface (A. Giarrusso, G. Ricci, I Tritto).1. Giulio Natta - His Life and Scientific Achievements (L. Porri).2. Precise Arguments on the Distribution of Stereospecific Active Sites on MgC12-Supported Ziegler-Natta Catalysts (B. Liu, et al.).3. Recent Data on the Number of Active Centers and Propagation Rate Constants in Olefin Polymerization with Supported ZN Catalysts (V. Zakharov, et al.).4. Comparison of Silyl Chromate and Chromium Oxide Based Olefin Polymerization Catalysts (K. Cann, et al.).5. Surface Physico-Chemical State of CO-Prereduced Phillips CrOx/SiO2 Catalyst and Unique Polymerization Behavior in the Presence of Al-Alkyl Cocatalyst (B. Liu, et al.).6. D/A-Metallocenes: The New Dimension in Catalyst Design (A. Starzewski).7. Microstructural Characteristics and Thermal Properties of ansa-Zirconcene Catalyzed Copolymers of Propene with Higher a-Olefins (M. Sacchi, et al.).8. Relative Reactivity Enhancement of (ME5Cp)2Zrc12 in Mixture with (1,2,4-Me3Cp)2ZrC1<sub&a mp
  • g t
  • 2during Ethene/1-Hexene Copolymerization (I. Bruaseth & E. Rytter).9. Sterically Demanding Bis (2-silylindenyl) Zirconium (IV) Dichlorides as Polymerisation Catalyst Precursors (A. Hannisdal, et al.).10. From Zirconium to Titanium: The Effect of the Metal in Propylene Polymerization Using Fluxional Unabridged Bicyclic Catalysts (E. Polo, et al.).11. New Polymers by Copolymerization of Ethylene and Norbornene with Metallocene Catalysts (W. Kaminsky, et al.).12. On the Ethylene-Norbornene Copolymerization Mechanism (I. Tritto, et al.).13. Living Random Copolymerization of Ethene and Norbornene Using ansa-Fluorenylamidodimethyltitanium Complex (T. Hasan, et al.).14. New Organic Supports for Metallocene Catalysts Applied in Olefin Polymerizations (M. Klapper, et al.).15. Heterogenization of Metalorganic Catalysts of Olefin Polymerization and Evaluation of Active Site Non-Uniformity (L. Novokshonova, et al.).16. Fluorenyl Based Syndiotactic Specific Metallocene Catalysts Structural Features, Origin of Syndiospecificity (A. Razavi, et al.).17. Zirconocene-Catalysed Propene Polymerisation: Kinetics, Mechanisms, and the role of the Anion (F. Song, et al.).18. Highly Active and Stereoselective Olefin Polymerization Catalysts Generated by the Transfer-Epimetalation of Olefins or Acetylenes with Dialkyltitanium (IV) Complexes: Three-Membered Metallocycles as Active Catalysts Sites (J. Eisch, et al.).19. Polymerization of Acrylate Monomers by Iron (II) Complexes Bearing Bis(imido) pyridyl or Phosphine Ligands (P. Castro, et al.).20. Styrene Polymerization by Ziegler-Natta Catalysts Based on Bis (Salicylaldiminate) nickel (II) Complexes and Methyl Aluminoxane (C. Carini, et al.).21. Observation and Identification of the Catalytically Active Species of Bis(Phenox-imine) Group 4 Transition Metal Complexes for Olefin Polymerization Using 1H NMR Spectroscopy (H. Makio & T. Fujita).22. Polymerization of Propene by Post-Metallocene Catalysts (M. Lamberti, et al.).23. Macromonomers and Coordination Polymerization (J. Lahitte, et al.).24. Polymerization of Norbornene with Co (II) Complexes (F. Pelascini, et al.).25. A Combined Density Functional Theory and Molecular Mechanics (QM/MMStudy of Single Site Ethylene Polymerization Catalyzed by [Cp{NC(tBu)2}TiR+] in the Presence of the Counterion, CH3B(C6F5)3-(K. Vanka, et al.).26. Experimental and Calculated Vibrational Spectra and Structure of Ziegler-Natta Catalyst Precursor: 50/1 Comilled MgC12-TiC14 (L. Brambilla, et al.).27. Defects Distribution of Metallocene and MgC12-Supported Ziegler-Natta Isotactic Poly(Propylenes) as Revealed by Fractionation and Crystallization Behaviors (R. Alamo).28. Structural Characterization and Mechanical Behavior of Metallocenic Copolymers of Ethylene and 5,7-Dimethylota-1,6-Diene (M. Cerrada, et al.).29. On-Line Monitoring and Fingerprint Technology: New Tools for the Development of New Catalysts and Polyolefin Materials (A. Tuchbreiter, et al.).30. Polymacromonomers with Polyolefin Branches Synthesized by Free-Radical homopolymerization of Polyolefin Macromonomer with a Methacryloyl End Group (H. Kaneko, et al.).31. Synthesis of Polyolefin Based Materials with Improved Thermo-Oxidative Stability (M. Dolatkhani, et al.).32. Polymerization with Fischer-Tropsch Olefins - A New Challenge in Polymer Science (I. Tincul, et al.).33. Propylene Polymerization in Liquid Monomer with a Ziegler-Natta Catalysts in Bench Scale Reactors. Kinetics and Model to Predict Reaction Yields (J. Vaquero, et al.).34. Comparative Analysis of the Clathrate Forms of Syndiotactic Polystyrene, Ply (P-methlstyrene) and Ply (m-methlstyrene) (V. Petraccone & O. Tarallo).

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