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  • Tuning of Open-shell Characters of a Terphenoquinone by Introducing a Benzodithiophene Unit

    Tomita Hiroshi , Sakamaki Daisuke , Noguchi Mariko , Nakano Motohiro , Seki Shu

    … This molecule exhibits the open-shell biradical characters resulting from the thermally accessible open-shell structure. … X-ray structure analysis and magnetic measurements clarify that this molecule has a closed-shell ground state, which is lower than the open-shell biradical state by 10.4 kJ mol<sup>−1</sup>. …

    Chemistry Letters 46(6), 805-807, 2017


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