Formation of TiC and SiC Refractory Compounds by Mechanical Alloying.
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- El-Eskandarany M. Sherif
- Institute for Materials Research, Tohoku University Mining and Petroleum Engineering Department, Faculty of Engineering, Al-Azhar University
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- Konno Toyohiko J.
- Institute for Materials Research, Tohoku University
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- Sumiyama Kenji
- Institute for Materials Research, Tohoku University
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- Suzuki Kenji
- Institute for Materials Research, Tohoku University
Bibliographic Information
- Other Title
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- Formation of TiC and SiC Refractory Com
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Abstract
Mechanical alloying via high energy ball-mill operated at room temperature has been used for preparing TiC and SiC compounds, starting from elemental Ti, Si and graphite powders. X-ray diffraction, transmission electron microscope, scanning electron microscope and infrared absorption have been used to follow the progress of the mechanical reactions between the reactant materials of Ti-C and Si-C, binary systems. A complete single phase of NaCl-type structure of Ti44C56, compound is yielded after 20 ks of milling. The lattice parameter (a0) of this compound was calculated to be 0.4326 nm. This end-product of Ti44C56 consists of fine grains of about 5 nm in diameter and possesses homogeneous powders with an average particle diameter of less than 0.5 μm in diameter. In Si-C binary system, a complete stoichiometric β-SiC phase was obtained after 1080 ks of milling. The a0 for final-product of β-SiC powders was calculated to 0.4357 nm. The existence of transverse optical (TO) and longitudinal optical (LO)-like phonon modes for β-SiC compound are observed. The internal structure of the particles are marked by fine cell-like features of about 6 nm.
Journal
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- Journal of the Japan Society of Powder and Powder Metallurgy
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Journal of the Japan Society of Powder and Powder Metallurgy 43 (5), 579-583, 1996
Japan Society of Powder and Powder Metallurgy
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Details 詳細情報について
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- CRID
- 1390001206307508096
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- NII Article ID
- 10002012107
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- NII Book ID
- AN00222724
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- ISSN
- 18809014
- 05328799
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- NDL BIB ID
- 3967164
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed