Preparation of Cellulose Derivatives with Long Alkylamino Groups in the Side Chains and Their Adsorption Behavior of Heavy Metal Ions.
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- Nakamura Shigeo
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University
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- Sanada Nae
- Department of Applied Chemistry, Faculty of Engineering, Kanagawa University
書誌事項
- タイトル別名
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- Preparation of Cellulose Derivatives wi
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6-(Alkylamino) deoxycelluloses were prepared from 6-chlorodeoxycellulose and n-alkylamines, CH3 (CH2)mNH2 (m=5, 11, 17), and their adsorption behavior of divalent heavy metal ions, Co2+, Ni2+, Cu2+ and Cd2+, was examined.<br>Metal ions were adsorbed on these alkylaminocelluloses in weakly acidic solution. The proportion of adsorbed metal ions increased with increasing pH of the solution and was dependent on the length of the alkyl chain in the order of n-stearylaminodeoxycellulose (m=17)> n-laurylaminodeoxycellulose (m=11)>n-hexylaminodeoxycellulose (m=5). The adsorptive activity of n-laurylaminodeoxycellulose was found to be in the order of Cu2+>Co2+, Cd2+>Ni2+. Since these adsorbents had a single coordination site in the pendant groups, the proportion of adsorption against metal ions was much lower than that of cellulose derivatives having two coordination sites in the pendant groups reported previously.
収録刊行物
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- 繊維学会誌
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繊維学会誌 53 (10), 467-470, 1997
社団法人 繊維学会
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詳細情報 詳細情報について
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- CRID
- 1390282679806050816
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- NII論文ID
- 130004074982
- 10002058325
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- NII書誌ID
- AN00131651
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- ISSN
- 18842259
- 00379875
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- NDL書誌ID
- 4324130
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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