多量化コバルトポルフィリン/高分子配位子系を表面修飾した電極による酸素還元 分子構造と酸素還元電極触媒活性の関係

書誌事項

タイトル別名
  • Oxygen Reduction by Electrodes Modified with Aggregated Cobalt-porphyrin/Polymer Ligand Systems: Relation between Molecular Structure and Electrocatalytic Activity for Oxygen Reduction.
  • タリョウカ コバルト ポルフィリン コウブンシ ハイイシケイ オ ヒョウメン
  • Relation between Molecular Structure and Electrocatalytic Activity for Oxygen Reduction
  • 分子構造と酸素還元電極触媒活性の関係

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抄録

Electrodes modified using aggregated cobalt-porphyrin/polymer ligand systems were prepared and electro-catalytic activity for oxygen (O2) reduction was investigated physicochemically. The maximum value of water yield due to O2 four-electron reduction was 56%. The apparent number of electrons involved in O2 reduction was 2.7 to 31. Two reactions due to O2 two- and four-electron reduction occurred on modified electrodes. Modification (adsorption) stability of the electrocatalyst system was over a few hours under hydrodynamic conditions.

収録刊行物

  • 表面技術

    表面技術 48 (12), 1218-1224, 1997

    一般社団法人 表面技術協会

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