Magnetoresistance of La-Sr-Mn Oxides Prepared by Oxidation of Melt-Quenched Alloy.

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  • 磁石・磁性材料の化学 II  液体急冷したLa‐Sr‐Mn合金の酸化と磁気抵抗特性
  • エキタイ キュウレイ シタ La-SrMn ゴウキン ノ サンカ ト ジキ テイコウ トクセイ

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Abstract

The La0.85Sr0.15Mn oxides with a perovskite structure and a negative magnetoresistance were easily prepared by oxidation of melt-quenched alloy tapes in air. The perovskite structure was obtained by oxidation at over 1073K. The magmetoresistance ratio at room temperature increase with oxidation temperature and reached 5% at 1373K. The annealing in O2 atomsphere enhanced the magnetoresistance ratio to 10%. Therefore, the oxidation process of the melt-quenched alloy is useful for the preparation of perovsky type La0.85Sr0.15Mn oxide with a negative magnetoresistance.

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