スクアレン酸化劣化挙動

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タイトル別名
  • Degradation by Oxidation of Squalene.
  • スクアレン ノ サンカ レッカ キョドウ

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抄録

An aerobic oxidation of squalene was carried out in a flow reactor system. Six peroxides obtained by this process were subjected by HPLC with UV, chemical luminescence detectors and iodometry. The oxidation was similar to that in the batch reactor system in which two periods of oxidation (induction and acceleration periods) were observed. In the acceleration period after the induction, squalene was oxidized by the series reactions with very high rates to form six peroxides. The peroxides were further decomposed and polymerized to carboxylic acids, ketones, aldehydes and high molecular weight products as tetramer.

収録刊行物

  • 日本油化学会誌

    日本油化学会誌 46 (11), 1361-1367, 1997

    公益社団法人 日本油化学会

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