Metal Uptake Properties of Polystyrene Resin Immobilized Polyamine and Formylsalicylic Acid Derivatives as Chelation Ion Exchangers.

• MAHMOUD Mohamed E.

  Chemistry Department, Faculty of Science, Alexandria University

• SOLIMAN Ezzat M.

  Chemistry Department, Faculty of Science, El-Minia University

• El-DISSOUKY Ali

  Chemistry Department, Faculty of Science, Alexandria University

Bibliographic Information

Other Title

• Metal Uptake Properties of Polystyrene

Abstract

Chloromethylated polystyrene resin was chemically modified with ethylenediamine, diethylenetnamine and triethylene- tetramine to polystyrene-polyamine resins (I-III). The latter resins were further reacted with two formylsalicylic acid isomers, 3-formylsalicylic acid and 5-formylsalicylic acid, to produce the cross-linking polystyrene-polyamine- formylsalicylic acid resins (IV-IX). The possible chemical structure of I-IX was confirmed from the elemental analysis and FT-IR studies. The applicability of I-IX to extraction of Fe(III), Cu(II), Cd(II) and Pb(II) from aqueous solutions was also studied by using the batch equilibrium technique in different buffer solutions and at different shaking time. Several trends were drawn out from the metal capacity values concerning the chemical structure of the amine and formylsalicylic acid moieties. The application of chelation ion exchange resins I-IX for selective extraction of certain metal ions was evaluated on the basis of the distribution ratio (D) showing the following order: D_Fe(III)_??_D_Cd(II)> D_Pb(II)>D_Cu(II).

Journal

• Analytical Sciences

  Analytical Sciences 13 (5), 765-769, 1997

  The Japan Society for Analytical Chemistry

Keywords

• Chelation ion exchanger
• polystyrene resin
• polyamine
• formylsalicylic acid
• iron
• copper
• cadmium
• lead

Details

• CRID: 1390282679228924800
• NII Article ID: 130003528218
• NII Article ID: 10002412839
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.13.765
• COI: 1:CAS:528:DyaK2sXmslShtrg%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 4317193
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4317193
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.13.765.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.13.765/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci1985/13/5/13_5_765/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed