Selective Ion Transfer Accompanied by a Respiration Mimetic Reaction at an Aqueous/Organic Solutions Interface.

• MAEDA Kohji

  Department of Chemistry, Kyoto Institute of Technology

• NISHIHARA Motoki

  Department of Chemistry, Kyoto Institute of Technology

• OHDE Hiroyuki

  Department of Chemistry, Kyoto Institute of Technology

• KIHARA Sorin

  Department of Chemistry, Kyoto Institute of Technology

Bibliographic Information

Other Title

• Selective Ion Transfer Accompanied by a Respiration Mimetic Reaction at the Aqueous/Organic Solutions Interface
• Selective Ion Transfer Accompanied by a

Abstract

When an aqueous solution (W) containing flavin mononucleotide, pyruvic acid and O₂ was put into contact with a nitrobenzene solution (NB) containing Na⁺, K⁺, valinomycin and a ferrocene derivative, CO₂ was evolved in W and Na⁺ was transferred from NB to W, though K⁺ remained in NB. The above-mentioned respiration mimetic reaction process, accompanied by the selective ion transfer, was elucidated by referring to the ion and electron transfer voltammograms at the W/NB interface and by taking into account the energetics of the coupling between the ion and electron transfers.

Journal

• Analytical Sciences

  Analytical Sciences 14 (1), 85-88, 1998

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204253414016
• NII Article ID: 10002414194
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.14.85
• COI: 1:CAS:528:DyaK1cXhtV2qtLo%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 4406427
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4406427
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.14.85.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.14.85/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/14/1/14_1_85/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed