Computational Aspects of Extraction Equilibrium and Distribution Potential of Electrolyte Distributed between Two Liquid Polar Phases.

• RAIS Jirí

  Nuclear Research Institute

書誌事項

タイトル別名

• Computational Aspects of Extraction Equ

抄録

It is proved that both “electrochemical” and “chemical” treatments of the equilibrium distribution of electrolytes between two polar solvents are correct, or in other words the use of electrochemical or chemical potentials is interchangeable. This is illustrated by calculation using a recursive iteration program for distribution of Sr²⁺ by dicarbollide anion in the presence of polyethyleneglycol. Several particular situations are described: the effect of common ion, limiting distribution coefficient and influence of protonized particles on distribution of cations.

収録刊行物

• Analytical Sciences

  Analytical Sciences 14 (2), 293-297, 1998

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390001204254649472
• NII論文ID: 130004439804
• NII論文ID: 10002415047
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.14.293
• COI: 1:CAS:528:DyaK1cXislGmtr0%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 4450410
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4450410
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.14.293.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.14.293/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/14/2/14_2_293/_pdf
• 本文言語コード: en
• データソース種別:
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  • NDL
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  • CiNii Articles
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