廃ホタテ貝殻焼成物を原料とするaragonite型軽質炭酸カルシウムの合成(第2報) -種結晶としてaragonite型炭酸塩を用いる方法- [in Japanese] Synthesis of Aragonite-type of Calcium Carbonate from Calcined Scallop Shell (2nd Report) - With carbonates of aragonite-structure as seeds - [in Japanese]
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Aragonite-type calcium carbonate was synthesized from calcined scallop shell using carbonates of orthorohombic structure (such as SrCO3) as seeds, by bubbling CO2 at ambient temperature. The products were examined by FTIR, SEM, EPMA, and XRD. The addition of SrCO3 increased aragonite content in the products, but BaCO3 and PbCO3 did not play the role of seed crystals due to the difference of their lattice parameters to those of aragonite, whereas lattice parameters of SrCO3 are the most similar to them. With increasing SrCO3 -addition, formation of aragonite was accelerated to a limit in the amount. Light calcium carbonate rich in aragonite was formed in agglegates consisting of needle-like crystals with large specific surface areas.
Shigen-to-Sozai 114(10), 709-713, 1998-09-25
The Mining and Materials Processing Institute of Japan