Methylene Insertion Reactions of Samarium Carbenoids into Boron–Hydrogen and Phosphorus–Hydrogen Bonds

• Tsuneo Imamoto

  Department of Chemistry, Faculty of Science, Chiba University

• Yoshinori Yamanoi

  Department of Chemistry, Faculty of Science, Chiba University

Abstract

A samarium carbenoid, generated from diiodomethane and samarium metal, reacts with phosphine–boranes to afford phosphine–monomethylborane in good yields. The P–H bonds of secondary phosphine–boranes or secondary phosphine oxides are subjected to methylene insertion with the same carbenoid to give the corresponding P-methylated derivatives.

Journal

• Chemistry Letters

  Chemistry Letters 25 (8), 705-706, 1996-08-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644039365376
• NII Article ID: 10002605553
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1996.705
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/25/8/705/56071292/cl.1996.705.pdf
• Data Source:
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  • CiNii Articles