Synthesis and Reactivity of <i>S</i>-Sulfiliminothiazynes

  • Masanori Ohkubo
    Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama UniversityGofuku, Toyama
  • Takayoshi Fujii
    Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama UniversityGofuku, Toyama
  • Shin Ono
    Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama UniversityGofuku, Toyama
  • Hiroyuki Morita
    Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama UniversityGofuku, Toyama
  • Toshiaki Yoshimura
    Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama UniversityGofuku, Toyama
  • Ernst Horn
    Tsukuba Advanced Research Alliance Center, Department of Chemistry, University of TsukubaTsukuba, Ibaraki
  • Soichi Sato
    Tsukuba Advanced Research Alliance Center, Department of Chemistry, University of TsukubaTsukuba, Ibaraki

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<jats:title>Abstract</jats:title> <jats:p>Reaction of S,S-diphenyl-S-fluorothiazyne with N-unsubstituted S,S-diphenylsulfilimine afforded the corresponding S-sulfiliminothiazyne. Measurement of the pKa value of S-sulfiliminothiazyne and its reactivity were examined. The molecular structure of the sulfonediiminosulfonium salt was determined by the X-ray crystallographic analysis.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (2), 153-154, 1997-02-01

    Oxford University Press (OUP)

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