A Novel Type of Amidato Coordination: The Metallocycle Rh-Rh-NH-C(Me)=O

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  • Vadim Yu Kukushkin
    Department of Chemistry, St. Petersburg State University198904 Stary Petergof, Russian Federation
  • Takanori Nishioka
    Department of Material Science, Faculty of Science, Osaka City UniversitySugimoto-cho, Sumiyoshi-ku, Osaka
  • Shigeyuki Nakamura
    Department of Material Science, Faculty of Science, Osaka City UniversitySugimoto-cho, Sumiyoshi-ku, Osaka
  • Isamu Kinoshita
    Department of Material Science, Faculty of Science, Osaka City UniversitySugimoto-cho, Sumiyoshi-ku, Osaka
  • Kiyoshi Isobe
    Department of Material Science, Faculty of Science, Osaka City UniversitySugimoto-cho, Sumiyoshi-ku, Osaka

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<jats:title>Abstract</jats:title> <jats:p>Treatment of [Rh2Cp*2(μ-CH2)2(μ-O2CO)] (Cp* = η5-C5Me5) with acetonitrile in aqueous solution followd by addition of KPF6 affords the Rh–Rh complex [Rh2Cp*2(μ-CH2)2(μ-NHC(=O)Me)][PF6], which has been characterized by elemental analysis, FAB-MS, 1H and 13C{1H} NMR spectroscopy, and X-ray crystallography. [Rh2Cp*2(μ-CH2)2(μ-η1:η1-NHC(=O)Me)][PF6] is the first example of an amidato complex where the ligand [NHC(=O)Me]− links the metal–metal site forming a novel type of metallocycle.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (2), 189-190, 1997-02-01

    Oxford University Press (OUP)

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