Porphyrin Architectures Constructed by CH···π Interactions: Synthesis and Crystal Structures of 5,10,15,20-Tetrakis(4-methylchalcogenophenyl)-21<i>H</i>,23<i>H</i>-porphyrins

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  • Ken-ichi Sugiura
    The Institute of Sciencific & Industrial Research (ISIR), Osaka University8-1 Mihogaoka, Ibaraki, Osaka
  • Kantaro Ushiroda
    The Institute of Sciencific & Industrial Research (ISIR), Osaka University8-1 Mihogaoka, Ibaraki, Osaka
  • Takanori Tanaka
    The Materials Analysis Center of ISIR, Osaka University8-1 Mihogaoka, Ibaraki, Osaka
  • Masami Sawada
    The Materials Analysis Center of ISIR, Osaka University8-1 Mihogaoka, Ibaraki, Osaka
  • Yoshiteru Sakata
    The Institute of Sciencific & Industrial Research (ISIR), Osaka University8-1 Mihogaoka, Ibaraki, Osaka

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<jats:title>Abstract</jats:title> <jats:p>Tetraphenylporphyrins substituted with methylchalcogeno groups (XMe: X = Te, Se, S, and O) were prepared. Crystal structure analysis revealed that a novel type of molecular alignments was achieved by intermolecular CH···π interactions between XCH3 and porphyrin π-systems.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (9), 927-928, 1997-09-01

    Oxford University Press (OUP)

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