Elementary Reactions of Nitrogen and Oxygen with Boron and Carbon at High Pressures and Temperatures

  • Yoo C. S.
    Lawrence Livermore National Laboratory, Livermore
  • Cynn H.
    Lawrence Livermore National Laboratory, Livermore
  • Nicol M. F.
    University of California, Los Angeles

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タイトル別名
  • Elementary Reactions of Nitrogen and Oxygen with Boron and Carbon at High Pressures and Tempeatures.
  • Elementary Reactions of Nitrogen and Ox

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The direct elementary reactions among the first and second row elements often yield novel superhard, high energy density, and wide band-gap optical materials. The reactions of oxygen and nitrogen with boron and carbon have been investigated at high pressures and temperatures by using an integrated technique of diamond-anvil cell, laser-heating, x-ray diffraction, Raman spectroscopy. A wide range of products has been synthesized and characterized in-situ at high pressures, including α-CO2, B2O3-I, B2O3-II, c-BN, h-BN, h'-BN, amorphous carbon nitrides. The elementary reactions occur exothermically and result in highly polycrystallized products with an exception in carbon-nitrogen reactions. The implication of the elementary reactions to energetic materials applications is discussed.

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