Synthesis of Azetidines from Imines with 2,3-Dihydrofuran under High Pressure.

• Oishi A.

  National institute of Materials and chemical research

• Taguchi Y.

  National institute of Materials and chemical research

• Tsuchiya T.

  National institute of Materials and chemical research

• Shibuya I.

  National institute of Materials and chemical research

Bibliographic Information

Other Title

• Synthesis of Azetidines from Imines wit

Abstract

6, 7-Aryl-2-oxa-7-azabicyclo[3. 2. 0]heptane compounds were obtained from arylimines with 2, 3-dihydrofuran under high pressure. When benzylidene aniline used as imine, 6, 7-diphenyl-2-oxa-7-azabicyclo[3. 2. 0]heptane was obtained 66% yield with 87% selectivity. This reaction was promoted by pressure and the yield and the selectivity of the reaction were increased by temperature. The mechanism of the reaction was considered zwittenonic route was favored.

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 7 1253-1255, 1998

  The Japan Society of High Pressure Science and Technology

Keywords

• imine
• 2, 3-dihydrofuran
• azetidine
• [2+2]cycloaddition
• high-pressure reaction

Details

• CRID: 1390001204382213376
• NII Article ID: 10002693603
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.7.1253
• ISSN: 13481940
• ISSN: 0917639X
• NDL BIB ID: 4494206
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4494206
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed