BEDO-TTFとC15-TCNQを混合した導電性LB膜の作製と評価

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タイトル別名
  • Preparation and Characterization of Conducting Langmuir-Blodgett Films of Binary Mixtures of BEDO-TTF and C15-TCNQ Molecules
  • BEDO-TTF ト C15-TCNQ オ コンゴウシタ ドウデンセイ LB

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Surface morphology and the electrical properties of LB films of binary mixtures of BEDO-TTF and C15-TCNQ were examined. The surface morphology of these LB films was observed by Atomic Force Microscopy (AFM). Surfaces of C15-TCNQ LB films were very smooth. Surfaces of BEDO-TTF+C15-TCNQ LB films were smooth, containing of small projections of BEDO-TTF crystals. The size and number of projections increased with increasing the composition of BEDO-TTF, and increasing the surface pressure at preparation condition. The value of conductivity of BEDO-TTF+C15-TCNQ LB films increased with increasing the composition of BEDO-TTF. The maximum conductivity was about 200S/m. The value of the conductivity of BEDO-TTF+C15-TCNQ LB films decreased with decreasing the temperature like semiconductors, however, the films (BEDO-TTF: C15-TCNQ=2:1) showed metaric behavior in the temperature range of 250-300K.

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