Polymerization of Styrene with Autoxidized Methyl Linoleate as Radical Initiator.

• KONDO Masaaki

  Faculty of Engineering, Shizuoka University

• AIKAWA Satoru

  Faculty of Engineering, Shizuoka University

• TASAKA Shigeru

  Faculty of Engineering, Shizuoka University

• INAGAKI Norihiro

  Faculty of Engineering, Shizuoka University

Bibliographic Information

Other Title

• リノール酸メチル自動酸化物を開始剤に用いたスチレンの重合
• リノールサン メチル ジドウ サンカブツ オ カイシザイ ニ モチイタ スチレ

Abstract

Autoxidized methyl linoleate was used as the initiator of radical polymerization of styrene and the influence of the oxidation levels on the structure of resulting polymers was investigated. Autoxidized methyl linoleate contained mainly monomers and oligomers with hydroperoxide moieties. They are able to work not only as an initiator but also as a crosslinking agent for the polymerization of styrene. The polymers synthesized by the oxidized products were not gelled and soluble in polar solvents completely. Therefore, the polymer was assumed to consist of linear (non-closslinked) chains having autoxidized methyl linoleate.

Journal

• KOBUNSHI RONBUNSHU

  KOBUNSHI RONBUNSHU 55 (3), 130-136, 1998

  The Society of Polymer Science, Japan

Keywords

• Methyl Linoleate
• Autoxidation
• Polymerization
• Styrene
• Radical

Details

• CRID: 1390001206521718528
• NII Article ID: 130004035282
• NII Article ID: 10003288275
• NII Book ID: AN00085011
• DOI: 10.1295/koron.55.130
• ISSN: 18815685
• ISSN: 03862186
• NDL BIB ID: 4436956
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4436956
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed