Catalytic Oxidation of α-Carbon of Ethers Utilizing Binuclear COpper (II) Complex of 7-Azaindole

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著者

    • MINAKATA Satoshi
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • IMAI Eiichiroh
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • OHSHIMA Yasuhito
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • INAKI Kanako
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • RYU Ilhyong
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • KOMATSU Mitsuo
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

Treatment of benzyl ethyl ether with a catalytic amount of binuclear copper(II) complex of 7-azaindole <B>1</B> under oxygen atmosphere at 80 °C produced ethyl benzoate in 10400% yield based on the catalyst. This reaction could be also applied to other ethers (e.g., alkyl benzyl ethers and dialkyl ethers) to give α-oxygenated products catalytically.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(1), 19-20, 1996-01-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003737906
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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