Photoreactions of Silyliron(II) Complexes Cp′Fe(CO)2SiMe3 (Cp′ = <i>η</i>5-C5H5, <i>η</i>5-C5Me5) with Di-<i>p</i>-tolylgermane (<i>p</i>-Tol)2GeH2

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  • Amr El-Maradny
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Hiromi Tobita
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Hiroshi Ogino
    Department of Chemistry, Graduate School of Science, Tohoku University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Photolysis of CpFe(CO)2SiMe3 (Cp = η5-C5H5) in the presence of (p-Tol)2GeH2 afforded a mixture of cis and trans isomers of diiron complexes Cp2Fe2(CO)2(μ-CO){μ-Ge(p-Tol)2} and Cp2Fe2(CO)2{μ-Ge(p-Tol)2}2. The Photostationary state with cis : trans = 85 : 15 was attained by the photolysis of either cis or trans isomer of the latter complex. In contrast, photoreaction of Cp*Fe(CO)2SiMe3 (Cp* = η5-C5Me5) with (p-Tol)2GeH2 gave a monoiron complex Cp*Fe(CO)2GeH(p-Tol)2.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 25 (1), 83-84, 1996-01-01

    Oxford University Press (OUP)

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