Electrochemical Deacetylation of 1,3-Dicarbonyl Compounds

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Mild deacetylation of 1,3-dicarbonyl compounds was achieved by halonium-ion mediated electrolysis. In this reaction, the supporting electrolyte including sodium halide NaX (X = Cl or Br) was essential since the reaction proceeded through substitution by a halonium ion, generated electrochemically at anode, on active methine carbons followed by base-catalyzed deacetylation, and was terminated by reductlve dehalogenation of the formed α-halo carbonyl compounds at cathode.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(2), 143-144, 1996-02-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003738688
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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