Reaction of 5-Phenyl-3H-1, 2-dithiol-3-one and Thione with [Rh (Cp^*) (CO)_2]・Formation of Metalladithiolene Rings via Rearrangement

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著者

    • NOZAWA Shouhei
    • Department of Chemistry, Faculty of Science and Technology, Sophia Univetsity
    • SUGIYAMA Toru
    • Department of Chemistry, Faculty of Science and Technology, Sophia Univetsity
    • AKIYAMA Takeo
    • Department of Chemistry, Faculty of Science and Technology, Sophia Univetsity
    • SUGIMORI Akira
    • Department of Chemistry, Faculty of Science and Technology, Sophia Univetsity

抄録

The reaction of [Rh(Cp<SUP>*</SUP>)(CO)<SUB>2</SUB>] (<B>1</B>) with 5-phenyl-3<I>H</I>-1,2-dithiol-3-one (<B>2</B>) affords two rhodiadithiolene complexes, a dimer of (<I>η</I><SUP>5</SUP>-pentamethylcyclopentadienyl)(1-oxo-2-benzylidene-1,2-ethanedithiolato)rhodium(III) (<B>4</B>) and (<I>η</I><SUP>5</SUP>-pentamethyl cyclopentadienyl)(1-phenyl-1,2-ethenedithiolato)rhodium(III) (<B>5</B>). 5-Phenyl-<I>3H</I>-1,2-dithiole-3-thione (<B>3</B>) reacts with <B>1</B> to afford only <B>5</B>. The formation of the complexes <B>4</B> and <B>5</B> is explained by a mechanism <I>via</I> the attack of coordinatively unsaturated "Rh(Cp<SUP>*</SUP>)(CO)" species to the S atom of <B>2</B>, followed by rearrangement.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(3), 191-192, 1996-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003738975
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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