A Chain Complex of Ruthenium (II, III) Cation Dimer Linked by a Nitroxide Radical, [Ru_2 (O_2CCMe_3) _4 (NITPh)] _n (BF_4) _n (NITPh=2-Phenyl-4, 4, 5, 5-tetramethyl-4, 5-dihydro-1H-imidazolyl-1-oxy-3-oxide)

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著者

    • HAHDA Makoto
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • SAYAMA Yasuyoshi
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • NUKADA Ryoji
    • Department of Chemistry, School of Science, Kwansei Gakuin University
    • HIROMITSU Ishiro
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • KASUGA Kuninobu
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University

抄録

A chain complex of ruthenium(II,III) cation dimer linked by the nitroxide radical, [Ru<SUB>2</SUB>(O<SUB>2</SUB>CCMe<SUB>3</SUB>)<SUB>4</SUB>(NITPh)]<I>n</I>(BF<SUB>4</SUB>)<I>n</I> (NITPh = 2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1<I>H</I>-imidazolyl-1-oxy-3-oxide) has been prepared and characterized. The structure with the alternated alignment of <I>S</I> = 3/2 (Ru(II,III) core) and <I>S</I> = 1/2 (NITPh) has been confirmed by the X-ray crystal analysis. The magnetic moment decreases monotonously with decrease of temperature.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(3), 201-202, 1996-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003739033
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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