New and Effective Synthesis of 7-Triethylsilylbaccatin III from 7β, 13α-Bistriethylsiloxy-1β, 2α, 10β-trihydroxy-9-oxo-4 (20), 11-taxadiene

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著者

    • SHIINA Isamu
    • Department of Applied Chemistry, Faculty of Science, Science University of Tokyo
    • SAITOH Masahiro
    • Department of Applied Chemistry, Faculty of Science, Science University of Tokyo
    • MISHIMURA Koji
    • Department of Applied Chemistry, Faculty of Science, Science University of Tokyo
    • SAITOH Katsuyuki
    • Department of Applied Chemistry, Faculty of Science, Science University of Tokyo
    • MUKAIYAMA Teruaki
    • Department of Applied Chemistry, Faculty of Science, Science University of Tokyo

抄録

7β,13α-Bistriethylsiloxy-1β,2α,10β-trihydroxy-9-oxo-4(20),11-taxadiene (<B>2</B>), derived from 10-deacetylbaccatin III <I>via</I> degradation of oxetane ring, was conveniently converted into 7-triethylsilylbaccatin III (<B>1</B>) by way of a new and effective method for constructing oxetane ring. Thus, the synthesis of a precursor of taxol from novel taxoid <B>2</B> was accomplished.

収録刊行物

  • Chemistry letters

    Chemistry letters 1996(3), 223-224, 1996-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10003739173
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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