Triple -Decker Trinuclear Porphinatoruthenium(II) Complexes Bridged with Pyrazine or 4,4′-Bipyridine-Preparation and Electrochemical Oxidation
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- Akira Endo
- Department of Chemistry, Faculty of Science and Technology, Sophia University
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- Uno Tagami
- Department of Chemistry, Faculty of Science and Technology, Sophia University
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- Yukari Wada
- Department of Chemistry, Faculty of Science and Technology, Sophia University
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- Miki Saito
- Department of Chemistry, Faculty of Science and Technology, Sophia University
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- Kunio Shimizu
- Department of Chemistry, Faculty of Science and Technology, Sophia University
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- Gen P Satô
- Department of Chemistry, Faculty of Science and Technology, Sophia University
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Abstract
<jats:title>Abstract</jats:title> <jats:p>Two triple-decker trinuclear porphinatoruthenium(II) complexes bridged with pyrazine (pyr) or 4,4′-bipyridine (4,4′-bpy), [{(CO)(oep)RuII}(μ-pyr){RuII(oep)}(μ-pyr){RuII(oep)(CO)}] (H2oep = octaethylporphine) and [{(CO)(tpp)RuII}(μ-4,4′-bpy){RuII(tpp)}(μ-4,4′-bpy){RuII(tpp)(CO)}] (H2tpp = tetraphenylporphine), have been prepared. The first trinuclear complex was electrochemically oxidized in four steps.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 25 (3), 243-244, 1996-03-01
Oxford University Press (OUP)
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Details
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- CRID
- 1360846644039303808
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- NII Article ID
- 10003739319
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles