Triple -Decker Trinuclear Porphinatoruthenium(II) Complexes Bridged with Pyrazine or 4,4′-Bipyridine-Preparation and Electrochemical Oxidation

  • Akira Endo
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Uno Tagami
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Yukari Wada
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Miki Saito
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Kunio Shimizu
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Gen P Satô
    Department of Chemistry, Faculty of Science and Technology, Sophia University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Two triple-decker trinuclear porphinatoruthenium(II) complexes bridged with pyrazine (pyr) or 4,4′-bipyridine (4,4′-bpy), [{(CO)(oep)RuII}(μ-pyr){RuII(oep)}(μ-pyr){RuII(oep)(CO)}] (H2oep = octaethylporphine) and [{(CO)(tpp)RuII}(μ-4,4′-bpy){RuII(tpp)}(μ-4,4′-bpy){RuII(tpp)(CO)}] (H2tpp = tetraphenylporphine), have been prepared. The first trinuclear complex was electrochemically oxidized in four steps.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 25 (3), 243-244, 1996-03-01

    Oxford University Press (OUP)

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